Thallium (I) fluorosulfonate

Crystal structure
__ Tl +      __ S 6+      __ O 2−      __ F -
Crystal system	orthorhombic
Space group	Pnma (No. 62)
Lattice parameters	a = 5.2205  Å b = 5.5141 Å c = 13.4378 Å
General
Surname	Thallium (I) fluorosulfonate
other names	Thallium (I) fluorosulfate
Ratio formula	TlSO 3 F
External identifiers / databases
CAS number 79752-01-5 Wikidata Q64728630
properties
Molar mass	303.43 g mol −1
safety instructions
GHS hazard labeling no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Thallium (I) fluorosulfonate , TlSO ₃ F is a chemical compound of thallium from the group of fluorosulfonates .

Extraction and presentation

The reaction of thallium (I) nitrate and fluorosulfonic acid produces thallium (I) fluorosulfonate in addition to nitric acid .

${\displaystyle {\ce {TlNO3 + HSO3F -> TlSO3F + HNO3}}}$

properties

The salt has an orthorhombic crystal system with the space group Pnma (space group no. 62) . The lattice parameters are a = 5.2205  Å , b = 5.5141 Å and c = 13.4378 Å. The cell volume is 386.83 Å ³ .

Individual evidence

1. ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
2. ↑ ^{a b} Tomasz Michałowski, Piotr J.Leszczyński, Michał Cyrański, Łukasz Dobrzycki, Armand Budzianowski, Wojciech Grochala: The missing crystal structures of fluorosulfates of monovalent cations: M (I) SO3F, M = Na, Rb and Tl . In: Journal of Fluorine Chemistry . August 2012, p. 116–120 , doi : 10.1016 / j.jfluchem.2012.05.004 .