In physics , the wave vector or wave number vector is a vector that is perpendicular to the wave front of a wave and is its magnitude , where is the wavelength . The unit of measurement for the components is 1 / m. In most cases it indicates the direction of propagation of the wave, but the direction of the Poynting vector for the flow of energy in electromagnetic waves in certain media can deviate from the wave vector.
A plane wave propagating in the direction can be written as:
With the components in the x, y and z directions
shows the wave vector in 3-dimensional k-space, also called reciprocal space , in a certain direction.
The magnitude of the wave vector is the circular wave number , hence the name wave number vector:
Wave vector and quantum numbers
Without further boundary conditions , for example in a vacuum, the wave vector of a particle can continuously assume any amount and any orientation. However, under certain circumstances the wave vector is a quantized quantity.
The restriction of particles to a finite space, for example in a potential well or the lattice of a solid , means that the steady state of the system can only assume discrete values. In this case, the wave vector is quantized, even if, strictly speaking, it does not represent quantum numbers. Rather, the wave vector is a function of quantum numbers, or its possible values can be counted using quantum numbers. This can be seen in analogy to the intrinsic energies of a quantum mechanical problem with a discrete spectrum : the index of the discrete energy is the quantum number, but not the energy itself.
Example: For the solutions of the Schrödinger equation of a three-dimensional, infinitely high potential well, the edge lengths apply
with the amplitude and the abbreviation
It is a non-negative integer and the index may have the values , or accept.
The stationary states of the particle, so by the quantum numbers , and characterized. Instead of naming a state using this number triple, the wave vector can also be used. However, the wave vector or one of its components must not be referred to as a quantum number, because on the one hand it is dimensional and on the other it is represented by real numbers .
A potential well with particles results in vectors in reciprocal space . When it comes to fermions , there are only a limited number of stationary states per wave vector. The number of these results from the amount of spin of the considered particles. Electrons are particles for which the amount of spin has the value . Such a spin can only assume two orientations with respect to a quantization axis . Therefore each wave vector in the potential well can be assumed to have a maximum of two electrons.
Wave vector and momentum
With photons ( Einstein equations ) as well as with matter waves (De Broglie relation) the vectorial momentum is proportional to the wave vector, with the reduced Planck constant as the proportionality factor:
- Charles Kittel: Introduction to Solid State Physics . 15th edition, Oldenbourg Verlag Munich, Munich 2013, ISBN 978-3-486-59755-4 .
- Bahaa EA Saleh, Malvin Carl Teich: Fundamentals of Photonics. 1st edition, Wiley-VCH Verlag GmbH & Co, Weinheim 2008, ISBN 978-3-527-40677-7 .
- Derivation of the photon wave vector (accessed December 28, 2015)