1,10-dibromodecane

Structural formula
General
Surname	1,10-dibromodecane
other names	Decamethylene dibromide
Molecular formula	C 10 H 20 Br 2
Brief description	beige solid
External identifiers / databases
ECHA InfoCard	100.021.701
PubChem	221483
Wikidata	Q57985172
properties
Molar mass	300.07 g mol −1
Physical state	firmly
density	1.335 g cm −3 (25 ° C)
Melting point	25-27 ° C
boiling point	160 ° C (15 mmHg)
solubility	practically insoluble in water; slightly soluble in ethanol; soluble in ether;
Refractive index	1.4912 (20 ° C)
safety instructions
GHS labeling of hazardous substances	no GHS pictograms
	no GHS pictograms
H and P phrases	H: no H-phrases
	P: no P-phrases
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

1,10-dibromodecane is a chemical compound from the group of aliphatic , saturated halogenated hydrocarbons .

Extraction and presentation

1,10-dibromodecane can be obtained by bromination of 1,10-decanediol .

properties

1,10-dibromodecane is a beige solid that is practically insoluble in water. It has a monoclinic crystal structure with the space group P 2 ₁ / c (space group no.14 ) (a = 5.4574, Å, b = 5.2814 Å, c = 21.088 Å, β = 92.897 °, z = 2) . Template: room group / 14

use

1,10-dibromodecane is used as an alkylating agent and as an intermediate in organic synthesis.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ data sheet 1,10-dibromodecane, 97% from Sigma-Aldrich , accessed on October 30, 2018 ( PDF ).
↑ ^a ^b ^c data sheet 1,10-dibromodecane, 97% from AlfaAesar, accessed on October 30, 2018 ( PDF )(JavaScript required) .
^ ^A ^b William M. Haynes: CRC Handbook of Chemistry and Physics, 94th Edition . CRC Press, 2016, ISBN 978-1-4665-7115-0 , pp. 150 ( limited preview in Google Book search).
↑ Rong Lu, Tetsuo Miyakoshi: Lacquer Chemistry and Applications . Elsevier, 2015, ISBN 978-0-12-803610-5 , pp. 157 ( limited preview in Google Book search).
↑ Isao Kanesaka, Sachie Matsuzawa et al. a .: Crystal structure of 1,10-dibromodecane and its infrared intensity in a urea clathrate and in the crystal. In: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 60, 2004, p. 2621, doi : 10.1016 / j.saa.2003.12.043 .
↑ Robert W. Bedle, George F. Huhn a. a .: Reaction Kinetics of a Condensation Polymer between 1,10-Dibromodecane and Hexamethylenediamine: Scale-Up Considerations. In: Organic Process Research & Development. 2, 1998, p. 105, doi : 10.1021 / op970243k .
^ J. van Alphen: On aliphatic polyamines. VIII. In: Recueil des Travaux Chimiques des Pays-Bas. 58, 1939, p. 544, doi : 10.1002 / recl.19390580610 .

[Sigma-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ data sheet 1,10-dibromodecane, 97% from Sigma-Aldrich , accessed on October 30, 2018 ( PDF ).

[Alfa-2] ta sheet 1,10-dibromodecane, 97% from AlfaAesar, accessed on October 30, 2018 ( PDF )(JavaScript required) .

[William_M._Haynes-3] A ^b William M. Haynes: CRC Handbook of Chemistry and Physics, 94th Edition . CRC Press, 2016, ISBN 978-1-4665-7115-0 , pp. 150 ( limited preview in Google Book search).

[Rong_Lu,_Tetsuo_Miyakoshi-4] Rong Lu, Tetsuo Miyakoshi: Lacquer Chemistry and Applications . Elsevier, 2015, ISBN 978-0-12-803610-5 , pp. 157 ( limited preview in Google Book search).

[DOI10.1016/j.saa.2003.12.043-5] Isao Kanesaka, Sachie Matsuzawa et al. a .: Crystal structure of 1,10-dibromodecane and its infrared intensity in a urea clathrate and in the crystal. In: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 60, 2004, p. 2621, doi : 10.1016 / j.saa.2003.12.043 .

[DOI10.1021/op970243k-6] Robert W. Bedle, George F. Huhn a. a .: Reaction Kinetics of a Condensation Polymer between 1,10-Dibromodecane and Hexamethylenediamine: Scale-Up Considerations. In: Organic Process Research & Development. 2, 1998, p. 105, doi : 10.1021 / op970243k .

[DOI10.1002/recl.19390580610-7] J. van Alphen: On aliphatic polyamines. VIII. In: Recueil des Travaux Chimiques des Pays-Bas. 58, 1939, p. 544, doi : 10.1002 / recl.19390580610 .