General structural formula of 2- (2-hydroxyphenyl) -2
H -benzotriazoles
2- (2-Hydroxyphenyl) -2 H -benzotriazoles (also 2-Hydroxyphenylbenzotriazoles or Hydroxyphenylbenzotriazoles ) are an important class of UV absorbers .
construction
They are substituted benzotriazoles with a phenyl group in the 2-position which carries a hydroxyl group in the ortho position .
Examples of 2- (2-hydroxyphenyl) -2 H -benzotriazoles
Surname
acronym
Structural formula
R 1
R 2
R 3
2- (2 H -enzotriazol-2-yl) -4-methylphenol
UV-P
-
methyl
-
2- (2 H -Benzotriazol-2-yl) -4,6-bis (2-phenyl-2-propanyl) phenol
UV-234
(2-propanyl) phenol
(2-propanyl) phenol
-
2- (2 H -enzotriazol-2-yl) -4,6-di- tert -butylphenol
UV-320
tert -butyl
tert -butyl
-
2- (5-chloro-2 H -benzotriazol-2-yl) -4-methyl-6- di - tert- butylphenol
UV-326
tert -butyl
methyl
chlorine
2- (5-chloro-2 H -benzotriazol-2-yl) -4,6-di- tert -butylphenol
UV-327
tert -butyl
tert -butyl
chlorine
2- (2 H -enzotriazol-2-yl) -4,6-di- tert -pentylphenol
UV-328
tert -pentyl
tert -pentyl
-
2- (2 H -Benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol
UV-329
-
1,1,3,3-tetramethylbutyl
-
2- (2 H -Benzotriazol-2-yl) -6- ( sec -butyl) -4- ( tert -butyl) phenol
UV-350
sec -butyl
tert -butyl
-
2,2′-methylenebis [6- (2 H -benzotriazol-2-yl) -4- (2,4,4-trimethyl-2-pentanyl) phenol]
UV-360
Dimer linked via methylene group
1,1,3,3-tetramethylbutyl
-
2- (2 H -Benzotriazol-2-yl) -6- (2-phenyl-2-propanyl) -4- (2,4,4-trimethyl-2-pentanyl) phenol
UV-928
(2-propanyl) phenol
1,1,3,3-tetramethylbutyl
-
use
2- (2-Hydroxyphenyl) -2 H -benzotriazoles are used as light stabilizers in paints and plastics .
Individual evidence
^ M. Grob et al .: Handbuch Kunststoff Additive . Ed .: R. D. Maier, M. Schiller. 4th, completely revised edition. Carl Hanser Verlag GmbH & Co. KG, 2016, light stabilizers, p. 155-467 , doi : 10.3139 / 9783446432918.002 .
↑ Entry on UV absorber. In: Römpp Online . Georg Thieme Verlag, accessed on January 25, 2020.
↑ a b Entry on 2- (2-Hydroxyphenyl) -2H-benzotriazole. In: Römpp Online . Georg Thieme Verlag, accessed on January 25, 2020.
<img src="https://de.wikipedia.org//de.wikipedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" title="" width="1" height="1" style="border: none; position: absolute;">