Fluorobenzyl alcohols

from Wikipedia, the free encyclopedia
Fluorobenzyl alcohols
Surname 2-fluorobenzyl alcohol 3-fluorobenzyl alcohol 4-fluorobenzyl alcohol
other names o -fluorobenzyl alcohol m -fluorobenzyl alcohol p -fluorobenzyl alcohol
Structural formula 2-fluorobenzyl alcohol 3-fluorobenzyl alcohol 4-fluorobenzyl alcohol
CAS number 446-51-5 456-47-3 459-56-3
PubChem 67969 68008 68022
Molecular formula C 7 H 7 FO
Molar mass 126.13 g mol −1
Physical state liquid
Melting point 22-24 ° C
boiling point 199-200 ° C
 
104-105 ° C
22  mmHg
204-206 ° C
 
GHS
labeling
no GHS pictograms
H-phrases no H-phrases no H-phrases no H-phrases
P-phrases no P-phrases no P-phrases no P-phrases

In chemistry, fluorobenzyl alcohols form a group of substances that are derived from both benzyl alcohol and fluorobenzene . The structure consists of a benzene ring with an attached hydroxymethyl group  (–CH 2 OH) and fluorine  (–F) as substituents . Their different arrangements ( ortho , meta or para ) result in three constitutional isomers with the empirical formula C 7 H 7 FO.

properties

The introduction of the fluorine atom changes the boiling point only slightly compared to benzyl alcohol (206 ° C).

Individual evidence

  1. a b Alfa Aesar catalog 2008/09, p. 981.
  2. a b FLUKA catalog 2001/2002, p. 657.
  3. a b Data sheet 3-Fluorobenzyl alcohol, 98% from Sigma-Aldrich , accessed on June 24, 2018 ( PDF ).
  4. Data sheet 2-Fluorobenzyl alcohol, 98% from Sigma-Aldrich , accessed on June 24, 2018 ( PDF ).
  5. Data sheet 4-Fluorobenzyl alcohol, 97% from Sigma-Aldrich , accessed on June 24, 2018 ( PDF ).
  6. Entry on benzyl alcohol in the GESTIS substance database of the IFA , accessed on June 24, 2018(JavaScript required) .

Web links

Commons : Fluorobenzyl Alcohols  - Collection of pictures, videos, and audio files