Fluorimide

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Structural formula
Structural formula of fluorimide
General
Surname Fluorimide
other names
  • 2,3-dichloro- N - (4-fluorophenyl) maleimide
  • 3,4-dichloro-1- (4-fluorophenyl) -1 H -pyrrole-2,5-dione
  • N - (4-fluorophenyl) dichloromaleimide
  • Spartcide
  • Late
Molecular formula C 10 H 4 Cl 2 FNO 2
Brief description

pale yellow crystals

External identifiers / databases
CAS number 41205-21-4
EC number 609-898-4
ECHA InfoCard 100.129.345
PubChem 93228
Wikidata Q19279670
properties
Molar mass 260.05 g mol −1
Physical state

firmly

Melting point

245-246 ° C

solubility

practically insoluble in water (5.9 mg l −1 at 20 ° C)

safety instructions
GHS labeling of hazardous substances
05 - Corrosive 06 - Toxic or very toxic 09 - Dangerous for the environment

danger

H and P phrases H: 318-331-411
P: 261-273-280-305 + 351 + 338-311
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Fluorimide is a chemical compound from the maleimide group and a fungicide that was introduced by Mitsubishi Chemical Industries in the 1970s .

Extraction and presentation

Fluorimide can be obtained by reacting 4-fluoroaniline and dichloromaleic acid.

use

Fluorimide is used against scab, monilia, powdery mildew and alternaria in fruit growing. It is also effective against fungal diseases in citrus, vine, coffee and rubber cultivation.

Admission

Fluorimide is only approved in Asia (Japan, Korea), but not in Europe.

Individual evidence

  1. a b c d Patent US3734927 : Novel maleimide and agricultural fungicide. Applied January 6, 1971 , published May 22, 1973 , Applicants: Kumiai Chemical Industry , Inventors: S. Kawada, H. Ito, K. Matsui, H. Kasugai.
  2. a b Crop Protection Handbook 2014 . 100th edition. MeisterPro, Willoughby, Ohio 2014, pp. 317 .
  3. a b Fluoroimide data sheet from Sigma-Aldrich , accessed on May 22, 2017 ( PDF ).
  4. Patent US4010182 : Method for producing N- (4-fluorophenyl) -2,3-dichloromaleimide. Applied on May 7, 1975 , published March 1, 1977 , Applicant: Mitsubishi Chemical Industries Ltd., Inventors: Kazuo Matsui, Taichiro Shigematsu, Tetsuya Shibahara, Makoto Nakazawa.
  5. ^ Food Safety Commission of Japan (FSCJ): Risk Assessment Report. Fluoroimide October 2013.
  6. ^ Directorate-General for Health and Food Safety of the European Commission: EU pesticide database ; Entry in the national directory of plant protection products in Switzerland ; Retrieved June 25, 2016.