Michler's ketone

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Structural formula
Structural formula of Michler's ketone
General
Surname Michler's ketone
other names
  • 4,4'-bis (dimethylamino) benzophenone
  • N , N , N ', N ' -Tetramethyl-4,4'-diaminobenzophenone
Molecular formula C 17 H 20 N 2 O
Brief description

colorless platelets

External identifiers / databases
CAS number 90-94-8
EC number 202-027-5
ECHA InfoCard 100.001.843
PubChem 7031
ChemSpider 6764
Wikidata Q418109
properties
Molar mass 268.36 g mol −1
Physical state

firmly

Melting point

172-175 ° C

solubility

very heavy in water (0.4 g l −1 at 20 ° C)

safety instructions
GHS hazard labeling from  Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary
08 - Dangerous to health 05 - Corrosive

danger

H and P phrases H: 350-341-318
P: 201-280-305 + 351 + 338-308 + 313
Authorization procedure under REACH

particularly worrying : carcinogenic ( CMR )

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Michler's ketone is an almost white solid in its pure state, but mostly a blue-gray solid in technical quality . It is named after its discoverer, the German chemist Wilhelm Michler (1846–1889).

Extraction and presentation

4,4'-bis (dimethylamino) benzophenone can be industrially obtained by reacting N , N -dimethylaniline with phosgene with Lewis catalysis by z. B. ZnCl 2 produce.

use

In the chemical industry, the compound is primarily used as a starting material for the synthesis of dyes such as B. Crystal Violet .

safety instructions

Michler's ketone is considered carcinogenic .

Individual evidence

  1. a b c d e Entry on Michler's ketone in the GESTIS substance database of the IFA , accessed on February 18, 2017(JavaScript required) .
  2. Entry on 4,4′-bis (dimethylamino) benzophenone in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
  3. Entry in the SVHC list of the European Chemicals Agency , accessed on July 15, 2014.