Neptunium series

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The Neptunium series is the natural decay series of the Neptunium isotope 237 Np. Your final nuclide is the thallium isotope 205 Tl; For a long time it was believed that the bismuth isotope 209 Bi was stable and the end point of the series. The series can also be continued beyond the neptunium to even heavier transuranic elements . The representation is only continued up to 241 Pu, which is produced in small quantities in nuclear reactors (extension in purple ).

The Neptunium series is also referred to as the "prehistoric" series, since the 237 Np present when the earth was formed has already completely decayed. Today the neptunium series exists again - albeit in an artificial way - because initial nuclides such as 241 Pu, 237 Np and 237 U are incubated in nuclear reactors as by- products or main products .

Radioactive decay series diagram.svg
Natural radioactive decay series: Neptunium series (purple)

4n + 1 row

Decay series of 237 Np (the very improbable series over the isotopes 221 Ra and 217 Rn are not shown); Z shows the atomic number (number of protons), N the number of neutrons of the isotopes
nuclide Decay HWZ E / MeV Decay product
241 Pu β - 99.9975%
α 0.0025%
14.4 a 0.021
5.14
241 At
237 U
241 On α 432.2 a 5.638 237 Np
237 U β - 6.75 d 0.519 237 Np
237 Np α 2.144 x 10 6 a 4,959 233 Pa
233 Pa β - 26,967 d 0.571 233 U
233 U α 1.592 x 10 5 a 4.909 229 Th
229 Th α 7880 a 5.168 225 ra
225 ra β - 14.9 d 0.357 225 Ac
225 Ac α 10.0 d 5.935 221 Fr
221 Fr α 99.9%
β - 0.1%
4.9 min 6.458
0.312
217 At
221 Ra
221 Ra α 28.0 s 6.886 217 para
217 at α 99.99%
β - 0.01%
32.3 ms 7.202
0.740
213 Bi
217 Rn
217 para α 0.54 ms 7,889 213 Po
213 bi β - 97.91%
α 2.09%
45.49 min 1.426
5.982
213 Po
209 Tl
213 Po α 4.2 ms 8.537 209 Pb
209 Tl β - 2.20 min 3,980 209 Pb
209 Pb β - 3.253 h 0.644 209 bi
209 bi α 1.9 · 10 19 a 3.137 205 Tl
205 Tl - stable - -

Individual evidence

  1. Pierre de Marcillac, Noël Coron, Gérard Dambier, Jacques Leblanc & Jean-Pierre Moalic: "Experimental detection of α-particles from the radioactive decay of natural bismuth", in: Nature , 2003 , Volume 422, Number 6934, p. 876 -878; doi : 10.1038 / nature01541 .