Nitrosyl tetrafluoroborate

Structural formula
General
Surname	Nitrosyl tetrafluoroborate
other names	Nitrosyl fluoroborate; Nitrosyl boron fluoride;
Molecular formula	NO [BF 4 ]
Brief description	colorless solid
External identifiers / databases
EC number	238-679-2
ECHA InfoCard	100.035.148
PubChem	151929
Wikidata	Q10859916
properties
Molar mass	116.82 g mol −1
Physical state	firmly
density	2.185 g cm −3
Sublimation point	250 ° C
solubility	Decomposes in water
safety instructions
GHS labeling of hazardous substances danger
H and P phrases	H: 314
	EUH: 031
	P: 260-303 + 361 + 353-305 + 351 + 338-301 + 330 + 331-405-501
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Nitrosyl tetrafluoroborate is a chemical compound from the group of nitrosyl compounds .

Extraction and presentation

Nitrosyl tetrafluoroborate can be obtained by reacting tetrafluoroboric acid with nitrous oxide and then subliming the resulting monohydrate in vacuo.

{\ displaystyle \ mathrm {2 \ H [BF_ {4}] + N_ {2} O_ {3} \ longrightarrow 2 \ NO [BF_ {4}] + H_ {2} O}}

properties

Nitrosyl tetrafluoroborate is a colorless, hygroscopic solid in the form of birefringent flakes. It decomposes in water with the escape of nitrogen oxides . It has an orthorhombic crystal structure with the space group Pbnm (space group no. 62, position 3) . Template: room group / 62.3

use

Nitrosyl tetrafluoroborate can be used to make NOF. It is also used as a nitrosating agent from secondary amines to nitrosamines, to convert aryl hydrazines to azides and other organic reactions.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g Data sheet Nitrosonium tetrafluoroborate, 98% from AlfaAesar, accessed on September 24, 2013 ( PDF )(JavaScript required) .
↑ ^a ^b ^c ^d Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 237.
^ Jean d'Ans, Ellen Lax, Roger Blachnik: Pocket book for chemists and physicists . Springer DE, 1998, ISBN 3-642-58842-5 , pp. 580 ( limited preview in Google Book search).

[Alfa-1] ↑ ^a ^b ^c ^d ^e ^f ^g Data sheet Nitrosonium tetrafluoroborate, 98% from AlfaAesar, accessed on September 24, 2013 ( PDF )(JavaScript required) .

[brauer-2] Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 237.

[Jean_d’Ans,_Ellen_Lax,_Roger_Blachnik-3] Jean d'Ans, Ellen Lax, Roger Blachnik: Pocket book for chemists and physicists . Springer DE, 1998, ISBN 3-642-58842-5 , pp. 580 ( limited preview in Google Book search).