Palladium (II) acetate

Structural formula
General
Surname	Palladium (II) acetate
other names	Pd (OAc) 2
Molecular formula	Pd (OCOCH 3 ) 2
Brief description	Solid
External identifiers / databases
EC number	222-164-4
ECHA InfoCard	100.020.151
PubChem	167845
Wikidata	Q6343207
properties
Molar mass	224.51 g mol −1
Physical state	firmly
Melting point	216.3–223.7 ° C (decomposition)
safety instructions
GHS labeling of hazardous substances danger
H and P phrases	H: 318
	P: 280-305 + 351 + 338 + 310
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Palladium (II) acetate is a chemical compound of palladium with the semi-structural formula Pd (CH ₃ COO) ₂ . Palladium (II) acetate dissolves in many organic solvents and is used as a catalyst for organic syntheses. In organometallic chemistry it serves as a precursor for other palladium complexes.

Manufacturing

Palladium (II) acetate can be produced by reacting palladium metal with a mixture of hot nitric acid and acetic acid . Depending on how it is manufactured, palladium (II) acetate can be present as a brown powder with a trimeric structure or as a pink powder with a chain structure.

Individual evidence

↑ ^a ^b ^c ^d ^e data sheet Palladium (II) acetate, ≥99.9% trace metals basis from Sigma-Aldrich , accessed on July 16, 2017 ( PDF ).
^ TA Stephenson, SM Morehouse, AR Powell, JP Heffer, G. Wilkinson: 667. Carboxylates of palladium, platinum, and rhodium, and their adducts. In: Journal of the Chemical Society . 1965, pp. 3632-3640, doi : 10.1039 / JR9650003632 .
↑ Sergei D. Kirik, Ruslan F. Mulagaleev, Alexander I. Blokhin: [Pd (CH ₃ COO) ₂ ] from X-ray powder diffraction data. In: Acta Crystallographica Section C Crystal Structure Communications. 60, 2004, pp. M449-m450, doi : 10.1107 / S0108270104016129 .

[Sigma-1] ↑ ^a ^b ^c ^d ^e data sheet Palladium (II) acetate, ≥99.9% trace metals basis from Sigma-Aldrich , accessed on July 16, 2017 ( PDF ).

[wilkinson-2] TA Stephenson, SM Morehouse, AR Powell, JP Heffer, G. Wilkinson: 667. Carboxylates of palladium, platinum, and rhodium, and their adducts. In: Journal of the Chemical Society . 1965, pp. 3632-3640, doi : 10.1039 / JR9650003632 .

[kiric-3] Sergei D. Kirik, Ruslan F. Mulagaleev, Alexander I. Blokhin: [Pd (CH ₃ COO) ₂ ] from X-ray powder diffraction data. In: Acta Crystallographica Section C Crystal Structure Communications. 60, 2004, pp. M449-m450, doi : 10.1107 / S0108270104016129 .