Pentanes

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Properties of the pentanes
Surname n -pentane Isopentane Neopentane
other names Pentane ( IUPAC ) 2-methylbutane 2,2-dimethylpropane
Refrigerant R-601 R-601a R-601b
Structural formula Pentane skeleton.svg Isopentane.svg Pentane 1.svg
CAS number 109-66-0 78-78-4 463-82-1
PubChem 8003 6556 10041
Molecular formula C 5 H 12
Molar mass 72.15 g mol −1
Brief description colorless liquids colorless gas
Melting point −130 ° C −160 ° C −16.6 ° C
boiling point 36 ° C 28 ° C 9.5 ° C
Vapor pressure (20 ° C) 562 mbar 761 mbar 1456 mbar
Vapor pressure (30 ° C) 815 mbar 1080 mbar 2100 mbar
Vapor pressure (50 ° C) 1590 mbar 2042 mbar 3700 mbar
density 0.63 g cm −3 0.62 g cm −3 0.6135 g cm −3
Solubility in H 2 O 39 mg l −1 50 mg l −1 33 mg l −1
Flash point −49 ° C −57 ° C <-7 ° C
lower explosion limit

(LEL)

1.1% by volume 1.3% by volume 1.3% by volume
33 g m −3 38 g m −3 40 g m −3
Upper explosion limit

(OEG)

8.7% by volume 7.6% by volume 7.5% by volume
260 g m −3 230 g m −3 230 g m −3
Ignition temperature 260 ° C 420 ° C 450 ° C

Pentanes are hydrocarbons with the empirical formula C 5 H 12 and count among the alkanes . There are three constitutional isomers : n- pentane , isopentane and neopentane .

The name is derived from the Greek "penta", five, the molecule has 5 carbon atoms. All larger alkane molecules are also named according to numerals

n- pentane and isopentane are low-boiling liquids that are still liquid at room temperature, but boil on warm skin. They only solidify well below –100 ° C. Neopentane has an even lower boiling point, so it is already gaseous even at room temperature. However, its melting point is much higher compared to the two isomers, the melting temperature of -16.6 ° C means that neopentane would be solid in a freezer.

All three isomers form colorless, clear liquids, the vapor pressure at a certain temperature increases from n-pentane to iso-pentane and - with a little more difference - further to neo-pentane. Pentanes also burn below the freezing point of water and are explosive when mixed with air in areas with a concentration of a few percent by volume.

Handling and storage as a liquid is made difficult by the high vapor pressure. Since the liquids are electrically non-conductive, there is a risk of electrical charging, spark discharge and ignition when pouring out.

Pentane can (out of date) be regarded as an amyl hydride. Amyl alcohol is pentanol.

According to Antoine , the vapor pressure curves can be approximated in the form log 10 (P) = A− (B / (T + C)) (P in bar, T in K ) in the specified temperature ranges with the following parameters:

Vapor pressure functions of the pentanes
T (K)
ranges
A. B. C.
n -pentane 268.8-341.37 3,9892 1070.617 −40.454
341.37-? ? ? ?
Isopentane 190.3-300.9 3.90935 1018,516 −40.081
300.9-453.5 3.97183 1021.864 −43.231
Neopentane 268.0-313.2 3.86373 0950.318 -36.329
313.2-3430 ? ? ?
343-433 4,61616 1478.868 41.256
Vapor pressure curves ( logarithmic ) of the pentanes (T = 0… 150 ° C) (green: neo-pentane)

Individual evidence

  1. all data was taken from the GESTIS database, the individual links are in the name line.
  2. Entry for CAS no. 109-66-0 in the GESTIS substance database of the IFA , accessed on January 11, 2017(JavaScript required) .
  3. Entry for CAS no. 78-78-4 in the GESTIS substance database of the IFA , accessed on January 12, 2017(JavaScript required) .
  4. Entry for CAS no. 463-82-1 in the GESTIS substance database of the IFA , accessed on January 12, 2017(JavaScript required) .
  5. a b Osborn, AG; Douslin, DR: Vapor-Pressure Relations for 15 Hydrocarbons in J. Chem. Eng. Data 19 (1974) 114-117.
  6. ^ DR Stull: Vapor Pressure of Pure Substances Organic Compounds , in: Ind. Eng. Chem. 39 (1947), pp. 517-540, doi : 10.1021 / ie50448a022 .
  7. Dawson, PP, Jr .; Silberberg, IH; McKetta, JJ: Volumetric Behavior, Vapor Pressures, and Critical Properties of Neopentane in J. Chem. Eng. Data 18 (1973) 7-15.