1,3-dichloro-2-butene

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Structural formula
Structural formula of 1,3-dichloro-2-butene
cis-trans mixture
General
Surname 1,3-dichloro-2-butene
other names
  • 1,3-dichlorobut-2-ene
  • 1,3-DCB
Molecular formula C 4 H 6 Cl 2
Brief description

colorless liquid

External identifiers / databases
CAS number
  • 926-57-8 (unspec.)
  • 10075-38-4 (2 Z -isomer)
  • 7415-31-8 (2 E isomer)
EC number 213-138-3
ECHA InfoCard 100,011,945
PubChem 13556
Wikidata Q60023051
properties
Molar mass 125 g mol −1
Physical state

liquid

density

1.161 g cm −3

Melting point

-81 ° C

boiling point

126 ° C

Vapor pressure
  • 15 hPa (20 ° C, cis )
  • 20 hPa (20 ° C, trans )
solubility

practically insoluble in water

Refractive index
  • 1.4735 (20 ° C, cis )
  • 1.4719 (20 ° C, trans )
safety instructions
GHS labeling of hazardous substances
02 - Highly / extremely flammable 06 - Toxic or very toxic 05 - Corrosive

danger

H and P phrases H: 226-301-331-314
P: 210-260-280-302 + 352-305 + 351 + 338-310
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

1,3-dichloro-2-butene is a chemical compound from the group of chlorinated hydrocarbons .

Extraction and presentation

1,3-Dichloro-2-butene can be obtained by reacting 2-chloro-1,3-butadiene and hydrogen chloride with copper (I) chloride as a catalyst. It is also a by-product of the manufacture of chloroprene from butenine .

Individual evidence

  1. a b c d e f g h i Entry on 1,3-dichloro-2-butene in the GESTIS substance database of the IFA , accessed on January 8, 2020(JavaScript required) .
  2. a b David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-152.
  3. ^ The equilibrium liquid-vapor of the system trans -1,3-dichloro-2-butene-2,3,4-trichloro-1-butene . In: Chem. Zvesti 23, 270-274 (1969).