2,5-bis (hydroxymethyl) furan

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Structural formula
Structural formula of 2,5-bis (hydroxymethyl) furan
General
Surname 2,5-bis (hydroxymethyl) furan
other names

BHMF

Molecular formula C 6 H 8 O 3
Brief description

dirty white to light yellow solid

External identifiers / databases
CAS number 1883-75-6
EC number 217-544-1
ECHA InfoCard 100.015.950
PubChem 74663
Wikidata Q4596786
properties
Molar mass 128.13 g mol −1
Physical state

firmly

Melting point

74-77 ° C

safety instructions
GHS labeling of hazardous substances
07 - Warning

Caution

H and P phrases H: 317-319
P: 280-305 + 351 + 338-411 + 235
Toxicological data

980 mg kg −1 ( LD 50ratoral )

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

2,5-bis (hydroxymethyl) furan is a furan that is produced by reduction from hydroxymethylfurfural (HMF), a degradation product of cellulose .

synthesis

2,5-bis (hydroxymethyl) furan can be prepared by reducing HMF on a Ni-Zr catalyst.

Individual evidence

  1. Entry on 2,5-furandimethanol at ChemicalBook , accessed on December 5, 2013.
  2. data sheet at Synquest
  3. a b data sheet furan-2,5-diyldimethanol from Matrix Scientific, accessed on April 25, 2018 (PDF).
  4. clearsynth: MSDS ( Memento from February 23, 2014 in the Internet Archive )
  5. Patent EP2233478B1 : Production of 2,5-bis- (hydroxymethyl) furan from 2,5- (hydroxymethyl) furaldehyde using a nickel-zirconium catalyst. Filed December 9, 2005 , published March 13, 2013 , applicant: Archer Daniels Midland , inventor: Alexandra J. Sanborn.