3,5-dibromanisole

Structural formula
General
Surname	3,5-dibromanisole
other names	1,3-dibromo-5-methoxybenzene
Molecular formula	C 7 H 6 Br 2 O
External identifiers / databases
EC number	625-375-3
ECHA InfoCard	100.153.878
PubChem	11021812
ChemSpider	9196994
Wikidata	Q223005
properties
Molar mass	265.93 g mol −1
Physical state	firmly
Melting point	40 ° C ; 34-38 ° C;
boiling point	124 ° C (13 h Pa )
safety instructions
GHS labeling of hazardous substances danger
H and P phrases	H: 301
	P: 301 + 310
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

3,5-dibromanisole is a chemical compound that is derived from both anisole and dibromobenzenes .

presentation

3,5-dibromanisole can be prepared from 3,5-dibromophenol by methylation with dimethyl sulfate .

properties

In contrast to the corresponding phenol, the nitration of 3,5-dibromanisole takes place only twice at positions 2 and 4; 3,5-dibromo-2,4-dinitroanisole is formed, which is converted into 3,5-dibromo-2, by ether cleavage. 4-dinitrophenol (melting point 146-147 ° C) can be converted.

The flash point of 3,5-dibromanisole is above 110 ° C.

Individual evidence

^ Dictionary of organic compounds, p. 1971 ( limited preview in Google book search).
↑ ^a ^b M. JJ Blanksma "Bromuration et nitration de phenol méta-substitues," in Rec Trav.. Chim , 1907 , 27 , pp. 25-41; Full text .
↑ ^a ^b ^c ^d ^e data sheet 3,5-dibromoanisole from Sigma-Aldrich , accessed on December 14, 2012 ( PDF ).
↑ ^a ^b M. Kohn, M. Heller: "About the exchangeability of halogen atoms and of nitro groups in some nitrohalophenol ethers. XIII. Communication on bromophenols", in: Monatshefte für Chemie , 1925 , 46 (1-2), p. 91– 100; doi : 10.1007 / BF01525493 .

[DOC-1] Dictionary of organic compounds, p. 1971 ( limited preview in Google book search).

[Blanksma-2] M. JJ Blanksma "Bromuration et nitration de phenol méta-substitues," in Rec Trav.. Chim , 1907 , 27 , pp. 25-41; Full text .

[Sigma-3] ↑ ^a ^b ^c ^d ^e data sheet 3,5-dibromoanisole from Sigma-Aldrich , accessed on December 14, 2012 ( PDF ).

[Kohn-4] M. Kohn, M. Heller: "About the exchangeability of halogen atoms and of nitro groups in some nitrohalophenol ethers. XIII. Communication on bromophenols", in: Monatshefte für Chemie , 1925 , 46 (1-2), p. 91– 100; doi : 10.1007 / BF01525493 .