3-octene

Structural formula
	; ;
	cis -form (above) trans -form (below)
General
Surname	3-octene
other names	Oct-3-en
Molecular formula	C 8 H 16
Brief description	colorless liquid with a characteristic odor
External identifiers / databases
EC number	209-779-3
ECHA InfoCard	100,008,892
Wikidata	Q30108402
properties
Molar mass	112.22 g mol −1
Physical state	liquid
density	0.716 g cm −3 ; 0.7152 g cm −3 ( cis ); 0.7212 g cm −3 ( trans );
Melting point	−126 ° C ( cis ); −110 ° C ( trans );
boiling point	123 ° C ( cis ); 121–222 ° C ( trans );
Vapor pressure	43 hPa (37 ° C, trans )
solubility	practically insoluble in water; soluble in ether, ethanol, acetone, benzene and chloroform;
Refractive index	1.4130 (20 ° C, trans );
safety instructions
GHS labeling of hazardous substances trans -3-octene danger
H and P phrases	H: 225
	P: 210-280-240-241-303 + 361 + 353-501
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

3-Octene is a chemical compound from the group of alkenes .

Isomerism

The unsymmetrically substituted double bond has E / Z isomerism , 3-octene therefore exists in two isomeric forms, as ( E ) - or trans -3-octene and ( Z ) - or cis -3-octene.

Extraction and presentation

3-octene can be prepared by isomerization of 1-octene are obtained, with about 20% trans -3-octene, 50% trans -2-octene , 10% cis -2-octene, 10% trans -4-octene and other isomers arising .

properties

3-octene is a colorless liquid with a characteristic odor.

use

3-Octene can be used for organic synthesis.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ data sheet trans-3-octene, 97% from AlfaAesar, accessed on June 2, 2017 ( PDF )(JavaScript required) .
↑ ^a ^b ^c ^d ^e ^f ^g William M. Haynes: CRC Handbook of Chemistry and Physics, 97th Edition . CRC Press, 2016, ISBN 978-1-4987-5429-3 , pp. 426 ( limited preview in Google Book search).
↑ External identifiers or database links to trans-3-octene : CAS number: 14919-01-8, EC number: 238-990-3, ECHA InfoCard: 100.035.431 , PubChem : 638228 , ChemSpider : 553784 , Wikidata : Q27160872 .
↑ External identifiers of or database links for cis-3-octene : CAS number: 14850-22-7, EC number: 238-912-8, ECHA InfoCard: 100.035.360 , PubChem : 5362722 , ChemSpider : 4515202 , Wikidata : Q27160868 .
↑ Ei-ichi Negishi: Handbook of Organopalladium Chemistry for Organic Synthesis, 2 Volume Set . John Wiley & Sons, 2003, ISBN 0-471-47381-2 , pp. 2787 ( limited preview in Google Book search).
↑ Supramolecular Catalysis . John Wiley & Sons, 2008, ISBN 978-3-527-62179-8 , pp. 207 ( books.google.de ).

[Alfa-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ data sheet trans-3-octene, 97% from AlfaAesar, accessed on June 2, 2017 ( PDF )(JavaScript required) .

[William_M._Haynes-2] ↑ ^a ^b ^c ^d ^e ^f ^g William M. Haynes: CRC Handbook of Chemistry and Physics, 97th Edition . CRC Press, 2016, ISBN 978-1-4987-5429-3 , pp. 426 ( limited preview in Google Book search).

[3] External identifiers or database links to trans-3-octene : CAS number: 14919-01-8, EC number: 238-990-3, ECHA InfoCard: 100.035.431 , PubChem : 638228 , ChemSpider : 553784 , Wikidata : Q27160872 .

[4] External identifiers of or database links for cis-3-octene : CAS number: 14850-22-7, EC number: 238-912-8, ECHA InfoCard: 100.035.360 , PubChem : 5362722 , ChemSpider : 4515202 , Wikidata : Q27160868 .

[Ei-ichi_Negishi-5] Ei-ichi Negishi: Handbook of Organopalladium Chemistry for Organic Synthesis, 2 Volume Set . John Wiley & Sons, 2003, ISBN 0-471-47381-2 , pp. 2787 ( limited preview in Google Book search).

[6] Supramolecular Catalysis . John Wiley & Sons, 2008, ISBN 978-3-527-62179-8 , pp. 207 ( books.google.de ).