5-nitroisoquinoline

Structural formula
General
Surname	5-nitroisoquinoline
Molecular formula	C 9 H 6 N 2 O 2
Brief description	yellow solid
External identifiers / databases
CAS number 607-32-9 EC number 210-133-8 ECHA InfoCard 100.009.213 PubChem 69085 Wikidata Q238550
properties
Molar mass	174.16 g mol −1
Physical state	firmly
Melting point	106-109 ° C
safety instructions
GHS labeling of hazardous substances Caution H and P phrases H: 315-319-335 P: 261-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

5-Nitroisoquinoline is a heterocyclic chemical compound, which consists of an isoquinoline skeleton with a nitro group in the 5-position .

presentation

5-Nitroisoquinoline can be made by nitrating isoquinoline. The nitration takes place with high selectivity in the 5-position. This selectivity contrasts with the low selectivity of the nitration of the isomeric quinoline , from which a mixture of equal parts of 5- and 8-nitroquinoline is obtained.

Individual evidence

1. ↑ ^{a b} Data sheet 5-nitroisoquinoline from AlfaAesar, accessed on July 18, 2010 ( PDF )(JavaScript required) .
2. ↑ ^{a b} Data sheet 5-Nitroisoquinoline from Sigma-Aldrich , accessed on March 18, 2011 ( PDF ).
3. ↑ JA Joules, K. Mills: Heterocyclic Chemistry , 5th Edition, pp. 177-199, Blackwell Publishing, Chichester, 2010, ISBN 978-1-4051-9365-8 .
4. ↑ MW Austin, JH Ridd: The kinetics and mechanism of heteroaromatic nitration. Part I. Quinoline , in: J. Chem. Soc. 1963 : 4204-4210; doi : 10.1039 / JR9630004204 .