Ammonium sulfite

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Structural formula
Structural formula of ammonium sulfite
General
Surname Ammonium sulfite
other names
  • Ammonium sulfite
  • Ammonium bisulfite
Molecular formula (NH 4 ) 2 SO 3
Brief description

white odorless solid

External identifiers / databases
CAS number
  • 10196-04-0 (anhydrous)
  • 7783-11-1 (monohydrate)
  • 17026-44-7 (solution)
EC number 233-484-9
ECHA InfoCard 100.030.428
PubChem 25041
Wikidata Q2336041
properties
Molar mass 116.14 g mol −1
Physical state

firmly

density

1.41 g cm −3 (monohydrate)

solubility
  • Easily soluble in water (324 g l −1 at 0 ° C)
  • practically insoluble in ethanol and acetone
safety instructions
GHS labeling of hazardous substances
07 - Warning

Caution

H and P phrases H: 315-319-335
EUH: 031
P: 261-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Ammonium sulfite is an inorganic chemical compound from the group of sulfites .

Extraction and presentation

Ammonium sulphite is formed during flue gas desulphurisation in which sulfur dioxide is washed out of the cooled flue gases after adding ammonia . It is also formed when ammonium thiosulfate decomposes .

properties

Ammonium sulfite is a flammable, white, odorless solid that is easily soluble in water. It decomposes when heated above 60–70 ° C.

use

Ammonium sulphite is used for the production of the food color ammonium sulphite color ( E150d ).

Individual evidence

  1. a b c d e f g Entry on ammonium sulfite in the GESTIS material database of the IFA , accessed on July 29, 2014(JavaScript required) .
  2. Entry on AMMONIUM SULFITE in the Hazardous Substances Data Bank , accessed on July 29, 2014.
  3. ^ AF Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 656.
  4. Werner Baltes, Reinhard Matissek: Food chemistry . Springer-Verlag, 2011, p. 258 ( limited preview in Google Book search).