Bromiodomethane

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Structural formula
Structural formula of bromiodomethane
General
Surname Bromiodomethane
Molecular formula BrCH 2 I.
Brief description

colorless liquid

External identifiers / databases
CAS number 557-68-6
EC number 628-284-7
ECHA InfoCard 100.156.567
PubChem 68407
Wikidata Q850475
properties
Molar mass 220.84 g mol −1
Physical state

liquid

density

2.93 g cm −3 (25 ° C)

boiling point

138-141 ° C

solubility

very soluble in chloroform

Refractive index

1.6382

safety instructions
GHS labeling of hazardous substances
05 - Corrosive 07 - Warning

danger

H and P phrases H: 315-318-335
P: 261-280-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Bromiodomethane is a chemical compound from the group of aliphatic and saturated halogenated hydrocarbons or dihalomethanes .

Occurrence

Bromiodomethane occurs naturally in some marine algae .

properties

Bromiodomethane is a colorless clear liquid that is very soluble in chloroform . It breaks down easily in sunlight, giving off bromine and iodine .

use

Bromiodomethane is used as a reagent for carbene insertion and rapid photodissociation reactions.

Web links

Commons : Bromiodomethane  - Collection of pictures, videos and audio files

Individual evidence

  1. a b c d e f g h i Datasheet Bromiodmethane, 97% from Sigma-Aldrich , accessed on March 29, 2016 ( PDF ).
  2. ^ A b William M. Haynes: CRC Handbook of Chemistry and Physics, 96th Edition . CRC Press, 2015, ISBN 978-1-4822-6097-7 , pp. 68 ( limited preview in Google Book search).
  3. ^ John W. Blunt, Murray HG Munro: Dictionary of Marine Natural Products with CD-ROM . CRC Press, 2007, ISBN 978-0-8493-8217-8 , pp. 244 ( limited preview in Google Book search).
  4. ^ S. Bailleux, D. Duflot, K. Taniguchi, S. Sakai, H. Ozeki, T. Okabayashi, WC Bailey: Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH 2 BrI. In: Journal of Physical Chemistry A . 118, 2014, p. 11744, doi : 10.1021 / jp510119e .
  5. Majed Chergui: Femtochemistry Ultrafast Chemical and Physical Processes in Molecular Systems Proceedings of Femtochemistry: The Lausanne Conference . World Scientific, 1996, ISBN 978-981-4548-26-7 , pp. 301 ( limited preview in Google Book search).