Bromiodomethane
Structural formula | ||||||||||||||||
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General | ||||||||||||||||
Surname | Bromiodomethane | |||||||||||||||
Molecular formula | BrCH 2 I. | |||||||||||||||
Brief description |
colorless liquid |
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External identifiers / databases | ||||||||||||||||
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properties | ||||||||||||||||
Molar mass | 220.84 g mol −1 | |||||||||||||||
Physical state |
liquid |
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density |
2.93 g cm −3 (25 ° C) |
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boiling point |
138-141 ° C |
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solubility |
very soluble in chloroform |
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Refractive index |
1.6382 |
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safety instructions | ||||||||||||||||
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As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C |
Bromiodomethane is a chemical compound from the group of aliphatic and saturated halogenated hydrocarbons or dihalomethanes .
Occurrence
Bromiodomethane occurs naturally in some marine algae .
properties
Bromiodomethane is a colorless clear liquid that is very soluble in chloroform . It breaks down easily in sunlight, giving off bromine and iodine .
use
Bromiodomethane is used as a reagent for carbene insertion and rapid photodissociation reactions.
Web links
Commons : Bromiodomethane - Collection of pictures, videos and audio files
Individual evidence
- ↑ a b c d e f g h i Datasheet Bromiodmethane, 97% from Sigma-Aldrich , accessed on March 29, 2016 ( PDF ).
- ^ A b William M. Haynes: CRC Handbook of Chemistry and Physics, 96th Edition . CRC Press, 2015, ISBN 978-1-4822-6097-7 , pp. 68 ( limited preview in Google Book search).
- ^ John W. Blunt, Murray HG Munro: Dictionary of Marine Natural Products with CD-ROM . CRC Press, 2007, ISBN 978-0-8493-8217-8 , pp. 244 ( limited preview in Google Book search).
- ^ S. Bailleux, D. Duflot, K. Taniguchi, S. Sakai, H. Ozeki, T. Okabayashi, WC Bailey: Fourier Transform Microwave and Millimeter-Wave Spectroscopy of Bromoiodomethane, CH 2 BrI. In: Journal of Physical Chemistry A . 118, 2014, p. 11744, doi : 10.1021 / jp510119e .
- ↑ Majed Chergui: Femtochemistry Ultrafast Chemical and Physical Processes in Molecular Systems Proceedings of Femtochemistry: The Lausanne Conference . World Scientific, 1996, ISBN 978-981-4548-26-7 , pp. 301 ( limited preview in Google Book search).