Butyl selenomercaptan

Structural formula
General
Surname	Butyl selenomercaptan
other names	Butyl selenol
Molecular formula	C 4 H 10 Se
External identifiers / databases
PubChem	5255143
Wikidata	Q130175
properties
Molar mass	137.08 g mol −1
Physical state	liquid
density	1.24 g cm −3
boiling point	114 ° C
safety instructions
H and P phrases	H: 331-301-373-410
	P: ?
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Butylselenomercaptan is an organic chemical compound of selenium and the selenium analogue of butanol .

Extraction and presentation

Butyl selenomercaptan can be obtained by reacting sodium hydrogen selenide solution with butyl chloride or bromide .

{\ displaystyle \ mathrm {NaSeH + BuBr \ longrightarrow BuSeH + NaBr}}

properties

Butyl selenomercaptan is a very bad smelling liquid. The smell is reminiscent of a combination of rotting cabbage, garlic, onions, burnt toast and digester gas. Like almost all thiols and selenols , butylselenol reacts as a very weak acid .

Individual evidence

↑ ^a ^b ^c L. Tschugaeff: About selenomercaptans and some derivatives of the same. In: Reports of the German Chemical Society, 42, 1909, pp. 49–54, doi : 10.1002 / cber.19090420107 .
↑ Entry on selenium compounds in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
↑ Not explicitly listed in Regulation (EC) No. 1272/2008 (CLP) , but with the specified labeling falls under the group entry selenium compounds with the exception of cadmium sulfoselenide, unless specifically listed in this appendix in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA ), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[Tschugaeff-1] L. Tschugaeff: About selenomercaptans and some derivatives of the same. In: Reports of the German Chemical Society, 42, 1909, pp. 49–54, doi : 10.1002 / cber.19090420107 .

[GESTIS-2] Entry on selenium compounds in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .

[CLP_100.240.771-3] Not explicitly listed in Regulation (EC) No. 1272/2008 (CLP) , but with the specified labeling falls under the group entry selenium compounds with the exception of cadmium sulfoselenide, unless specifically listed in this appendix in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA ), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .