Cadmium hexafluorosilicate

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Structural formula
Cadmium ion Structure of the hexafluorosilicate ion
Crystal system

trigonal

Space group

R 3 (No. 148)Template: room group / 148

General
Surname Cadmium hexafluorosilicate
other names

Cadmium fluorosilicate

Molecular formula CdSiF 6
Brief description

colorless solid

External identifiers / databases
CAS number
  • 17010-21-8
  • 18972-58-2 (hexahydrate)
EC number 241-084-0
ECHA InfoCard 100.037.334
PubChem 197153
ChemSpider 15382569
Wikidata Q62197983
properties
Molar mass 254.49 g mol −1
Physical state

firmly

solubility

easily soluble in water (20 ° C)

safety instructions
GHS hazard labeling from  Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary
06 - Toxic or very toxic 08 - Dangerous to health 09 - Dangerous for the environment

danger

H and P phrases H: 301-331-351-373-410
P: ?
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Cadmium hexafluorosilicate, CdSiF 6 is a chemical compound of cadmium from the group of hexafluorosilicates .

Extraction and presentation

The hexahydrate of cadmium hexafluorosilicate can be obtained by reacting cadmium carbonate with hexafluoridosilicic acid.

properties

Cadmium hexafluorosilicate is a crystalline, colorless solid that is easily soluble in water. The hexahydrate gives off water of crystallization at 170 ° C. It has a crystal structure with the space group R 3 (space group no. 148) . Template: room group / 148

toxicology

The inhalation or ingestion of the compound is toxic. Cadmium hexafluorosilicate is suspected of causing cancer and organ damage.

literature

  • Ganesh Thakur, AL Verma: Raman spectroscopic study of phase transformation in single crystals of cadmium fluorosilicate hexahydrate . John Wiley & Sons Ltd., June 1989, doi : 10.1002 / jrs.1250200605 .

Individual evidence

  1. a b c d e Entry on cadmium hexafluorosilicate in the GESTIS substance database of the IFA , accessed on March 16, 2019 (JavaScript required)
  2. Entry on cadmium hexafluorosilicate (2−) in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on December 15, 2019. Manufacturers or distributors can expand the harmonized classification and labeling .
  3. RJ Meyer: Cadmium system number 33 . Springer-Verlag, 2013, ISBN 978-3-662-11295-3 , pp. 154 ( limited preview in Google Book search).
  4. R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 370 ( limited preview in Google Book search).
  5. Ganesh Thakur, AL Verma: Raman spectroscopic study of phase transformation in single crystals of cadmium fluorosilicate hexahydrate. In: Journal of Raman Spectroscopy. 20, 1989, p. 367, doi : 10.1002 / jrs.1250200605 .