Gold (I) iodide

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Crystal structure
Structural formula of gold (I) iodide
__ Au +      __ I -
General
Surname Gold (I) iodide
other names

Gold monoiodide

Ratio formula AuI
Brief description

yellow solid

External identifiers / databases
CAS number 10294-31-2
EC number 233-656-3
ECHA InfoCard 100.030.584
PubChem 82526
Wikidata Q4202650
properties
Molar mass 323.87 g mol −1
Physical state

firmly

density

8.25 g cm −3  (25 ° C)

Melting point

120 ° C (decomposition)

solubility
  • slow decomposition in water
  • soluble in liquid ammonia
  • soluble in alkali iodides and alkali cyanides
safety instructions
GHS labeling of hazardous substances
07 - Warning

Caution

H and P phrases H: 315-319-335
P: 261-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Gold (I) iodide is an inorganic chemical compound of gold from the group of iodides .

Extraction and presentation

Gold (I) iodide can be obtained by reacting a tetrachloridoauric acid solution with potassium iodide . It is also possible to manufacture by reacting gold and iodine in a protective atmosphere at around 390 ° C.

properties

Gold (I) iodide is a yellow, crystalline powder that gradually decomposes on contact with water, humidity or light. It has a tetragonal crystal structure with the space group P 4 2 / ncm (space group no. 138) , a = 4.359 Å , c = 13.711 Å. Template: room group / 138

Individual evidence

  1. a b c d e f data sheet Gold (I) iodide, 99.9% trace metals basis from Sigma-Aldrich , accessed on April 4, 2013 ( PDF ).
  2. a b c d Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3 , p. 1014.
  3. ^ Dale L. Perry: Handbook of Inorganic Compounds, Second Edition . Taylor & Francis US, 2011, ISBN 1-4398-1462-7 , pp. 486 ( limited preview in Google Book search).