Hexanenitrile
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| General | |||||||||||||||||||
| Surname | Hexanenitrile | ||||||||||||||||||
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| Molecular formula | C 6 H 11 N | ||||||||||||||||||
| Brief description |
colorless liquid |
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| properties | |||||||||||||||||||
| Molar mass | 97.16 g mol −1 | ||||||||||||||||||
| Physical state |
liquid |
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| density |
0.81 g cm −3 |
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| Melting point |
−80 ° C |
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| boiling point |
164 ° C |
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| solubility |
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| Refractive index |
1.406 (20 ° C) |
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| As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C | |||||||||||||||||||
Hexanenitrile is a chemical compound from the group of nitriles .
Occurrence
Hexanenitrile has been detected in tobacco smoke .
Extraction and presentation
Hexanenitrile can be obtained by reacting 1-chloropentane or 1-bromopentane with sodium cyanide , although other synthetic routes are also known.
properties
Hexanenitrile is a colorless liquid that is practically insoluble in water.
safety instructions
The vapors of hexanenitrile can form an explosive mixture with air ( flash point 43 ° C).
Web links
- Ole John Nielsen, Cecilie Litske Carstens u. a .: Atmospheric chemistry of hexanenitrile: Kinetics and products of the gas-phase reactions of CH 3 (CH 2 ) 4 CN with Cl atoms and OH radicals. In: Chemical Physics Letters . 688, 2017, pp. 7-10; doi : 10.1016 / j.cplett.2017.09.030 .
Individual evidence
- ↑ a b c d e f g h i j Entry on hexanenitrile in the GESTIS substance database of the IFA , accessed on January 1, 2019(JavaScript required) .
- ↑ a b c d Datasheet Hexanenitrile, 98% from Sigma-Aldrich , accessed on January 1, 2019 ( PDF ).
- ↑ David R. Lide: CRC Handbook of Chemistry and Physics A Ready-reference Book of Chemical and Physical Data . CRC Press, 1995, ISBN 978-0-8493-0595-5 , pp. 308 ( limited preview in Google Book search).
- ↑ Alan Rodgman, Thomas A. Perfetti: The Chemical Components of Tobacco and Tobacco Smoke, Second Edition . CRC Press, 2013, ISBN 978-1-4665-1548-2 , pp. 1886 ( limited preview in Google Book search).
- ↑ Michael B. Smith: Organic Synthesis . Academic Press, 2016, ISBN 978-0-12-800807-2 , pp. 548 ( limited preview in Google Book search).
- ↑ J. Org. Chem., 1960, 25 (2), pp. 257-258
- ^ Alan R. Katritzky, Steven V. Ley, Otto Meth-Cohn, Charles Wayne Rees: Comprehensive Organic Functional Group Transformations: Synthesis: carbon with one heteroatom attached by a single bond . Elsevier, 1995, ISBN 978-0-08-042323-4 , pp. 1057 ( limited preview in Google Book search).