N , 2-dimethylaniline

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Structural formula
Structural formula of N-methyl-o-toluidine
General
Surname N , 2-dimethylaniline
other names
  • N -methyl- o -toluidine
  • N -methyl-2-toluidine
Molecular formula C 8 H 11 N
Brief description

light yellow to brown liquid

External identifiers / databases
CAS number 611-21-2
EC number 210-260-9
ECHA InfoCard 100.009.329
PubChem 69137
ChemSpider 62353
Wikidata Q1959580
properties
Molar mass 121.18 g mol −1
Physical state

liquid

density

0.981 g cm −3

boiling point

208 ° C

solubility

little in water (16.6 g l −1 at 25 ° C)

Refractive index

1.5649 (20 ° C)

safety instructions
GHS hazard labeling from  Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary
06 - Toxic or very toxic 08 - Dangerous to health

danger

H and P phrases H: 301-311-331-373-412
P: 261-273-280-301 + 310-311
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

N , 2-Dimethylaniline is a chemical compound from the group of dimethylanilines .

properties

N , 2-Dimethylaniline is a light yellow to brown liquid that is very sparingly soluble in water.

use

N , 2-Dimethylaniline is used for palladium- catalyzed coupling reactions and aminations of bromoindazoles .

safety instructions

The vapors of N , 2-dimethylaniline can form an explosive mixture with air ( flash point 93 ° C).

Individual evidence

  1. a b c d e f g h Entry on N-methyl-o-toluidine in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
  2. David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-192.
  3. Entry on N-methyl-o-toluidine in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
  4. Data sheet N-Methyl-o-toluidine, ≥ 95% from Sigma-Aldrich , accessed on January 27, 2012 ( PDF ).