Aluminum sodium silicate

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General
Surname Aluminum sodium silicate
other names

Sodium aluminum silicate

Ratio formula Na 12 (AlO 2 ) 12 (SiO 2 ) 12 ⋅ x H 2 O
Brief description

white odorless solid

External identifiers / databases
CAS number
  • 1344-00-9
PubChem 19758701
Wikidata Q724424
properties
Molar mass 142.05 g mol −1
Physical state

firmly

density

2.02 g cm −3

solubility

practically insoluble in water (68–79 mg · l −1 at 20 ° C)

safety instructions
GHS labeling of hazardous substances
no GHS pictograms
H and P phrases H: no H-phrases
P: no P-phrases
Toxicological data

> 27 g kg −1 ( LD 50ratoral )

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Aluminum sodium silicate (also sodium aluminum silicate ) describes a chemical compound from the group of aluminosilicates with a variable water of crystallization content , which is used as a food additive under the abbreviation E 554 .

Occurrence

Aluminum sodium silicate occurs naturally as the minerals trinepheline and carnegieite .

Extraction and presentation

Aluminum sodium silicate can be obtained by hydrothermal synthesis from sodium hydroxide , aluminum oxide and silicon dioxide or from water glass and sodium aluminate .

properties

Depending on how it is manufactured, aluminum sodium silicate is a crystalline or amorphous white odorless solid that is practically insoluble in water, but dissolves in acids with decomposition. Its aqueous dispersion has an alkaline reaction.

use

Aluminum sodium silicate is used as a filler in industry. It is approved in the EU as a food additive with the number E 554 with maximum quantity restrictions of 10 grams per kilogram for certain foods, for seasonings and food supplements also without maximum quantity restriction ( quantum satis ). Sodium aluminum silicates are used in paper production to improve the optical properties and to reduce the bleeding through of printing inks. They are also used as water softeners in detergents.

Individual evidence

  1. a b c d e f g h Entry on aluminum sodium silicate in the GESTIS substance database of the IFA , accessed on November 19, 2016(JavaScript required) .
  2. Shmuel Yannai: Dictionary of Food Compounds with CD-ROM, Second Edition . CRC Press, 2012, ISBN 978-1-4200-8351-4 , pp. 52 ( limited preview in Google Book search).
  3. a b Entry on sodium aluminum silicate. In: Römpp Online . Georg Thieme Verlag, accessed on June 16, 2019.
  4. Detlef Gysau: Fillers Basics and Applications . Vincentz Network GmbH & Co KG, 2006, ISBN 978-3-87870-337-2 , p. 119 ( limited preview in Google Book search).
  5. Zusatzstoffe-online.de: sodium aluminum silicate
  6. Werner Baumann, Herberg-Liedtke: Paper chemicals data and facts on environmental protection . Springer-Verlag, 2013, ISBN 978-3-642-58040-6 , pp. 68 ( limited preview in Google Book search).
  7. Michael Jessner: Chemistry II learning aid organic chemistry . BoD - Books on Demand, 2014, ISBN 978-3-7357-8059-1 , pp. 48 ( limited preview in Google Book search).