Quadrupole

Construction of an electrical quadrupole for the special case of a square arrangement.
The charge of the red points is + Q, that of the blue points is −Q.

Potential of a real electric quadrupole

Potential of an electrical point quadrupole

A quadrupole arises from the arrangement shown opposite of two oppositely identical electrical or magnetic dipoles with any distance vector, typically named. ${\ displaystyle {\ vec {a}}}$

In general, any charge or current distribution can be assigned a second order multipole moment , provided it does not have certain symmetries . For this purpose, the actual potential is approximated by a Taylor expansion . This results in this multipole expansion u. a. also a quadrupole moment .

Electric quadrupole

An electric quadrupole can consist of two equally large positive and two equally large negative charges that form two oppositely equal dipoles. In the simplest case, the four charges are located in an alternating arrangement at the corners of a parallelogram (usually even a square ).

The definition is mathematically precise by means of a limit value process known as "quadrupole limit" , in which the area of the parallelogram converges to zero , while at the same time the charge strength of the charges at the corners of the parallelogram diverges in such a way that the product remains constant, for example where the constant should be positive. ${\ displaystyle \ {\ lim _ {a \ to 0; \, a ^ {2} Q = {\ text {const.}}} \ dots \} \ ,,}$

The quadrupole potential results from the superposition ( superposition ) of the dipole potentials : ${\ displaystyle \ phi _ {\ text {Q}}}$ ${\ displaystyle \ phi _ {\ text {D}}}$

{\ displaystyle {\ begin {aligned} \ phi _ {\ text {Q}} ({\ vec {r}}) & = \ phi _ {\ text {D}} \ left ({\ vec {r}} + {\ dfrac {\ vec {a}} {2}} \ right) - \ phi _ {\ text {D}} \ left ({\ vec {r}} - {\ dfrac {\ vec {a}} {2}} \ right) \\\ & = {\ vec {a}} \ cdot {\ vec {\ nabla}} \ phi _ {\ text {D}} ({\ vec {r}}) + { \ mathcal {O}} (| {\ vec {a}} | ^ {3}) \ end {aligned}}}

In the transition to the last equation, the Taylor expansion was used and terms of the order of magnitude were neglected. ${\ displaystyle | {\ vec {a}} | ^ {3}}$

Obtained from the multipole with the Kronecker delta the quadrupole moment tensor with SI unit C · m²: ${\ displaystyle \ delta}$ ${\ displaystyle Q}$

{\ displaystyle Q_ {kl} = \ sum _ {i = 1} ^ {n} q_ {i} (3r_ {ik} \, r_ {il} - (r_ {i}) ^ {2} \, \ delta _ {kl})}

or for continuous load distribution :

{\ displaystyle Q_ {kl} = \ int \ rho ({\ vec {r}} \, ') \ cdot (3r' _ {k} \, r '_ {l} - (r') ^ {2} \, \ delta _ {kl}) \ cdot d ^ {3} r '}

It can be seen that the quadrupole tensor is symmetrical and without a trace. Due to the symmetry, only three of the six off-diagonal elements are independent, the lane clearance limits the three diagonal elements to two independent ones. The nine entries are therefore restricted by five degrees of freedom, so that the calculation can often be shortened.

Alternatively, the potential can also be represented as:

{\ displaystyle {\ begin {aligned} \ phi _ {\ text {Q}} ({\ vec {r}}) & = {\ frac {1} {8 \ pi \ varepsilon _ {0}}} {\ frac {{\ vec {r}} ^ {T} \ cdot Q \ cdot {\ vec {r}}} {r ^ {5}}} \\ & = {\ frac {1} {8 \ pi \ varepsilon _ {0}}} {\ frac {r_ {i} \ cdot Q_ {ij} \ cdot r_ {j}} {r ^ {5}}} \ end {aligned}}}

in which

the Einstein notation was used and
${\ displaystyle \ varepsilon _ {0}}$ is the electric field constant .

Applications

In practice, each arrangement of four alternately polarized electrodes is abbreviated to “quadrupole”, even if it does not generate a pure quadrupole field.

In AC operation, this arrangement allows only particles with a certain mass to charge ratio to pass through a beam of charged particles flying along the axis. Therefore this arrangement is used in mass spectrometers .

Another application of an electric quadrupole is the radio frequency quadrupole accelerator .

Magnetic quadrupole

In the simplest case, a magnetic quadrupole consists of two oppositely directed magnetic dipoles spaced apart . ${\ displaystyle {\ vec {a}}}$

Applications:

Quadrupole magnet : focusing magnet in particle accelerators and particle beam guides

selective separation in mass spectrometry systems

together with nuclear magnetic resonance spectroscopy : statements about the local geometry of the atomic nucleus in solids .

A spherical magnetic quadrupole field can be generated , for example, with a Maxwell coil .

Gravity

Illustration of the gravitational quadrupole moment: a homogeneous, spherical mass distribution deformed to an ellipsoid has a quadrupole moment in addition to the monopole.

In contrast to electromagnetism, there are only positive charges for gravitation , the masses . Therefore, a gravitational quadrupole cannot be defined using two dipoles as above. Nevertheless, mass distributions have a quadrupole moment, for example the earth, because it is not a perfect sphere: The flattening of the earth means that compared to an exactly spherical mass distribution (pure monopole) there is "missing" mass at the poles and an "excess" at the equator ("Equatorial Bulge"). Some celestial mechanical phenomena, such as the precession of the earth's axis and the dynamic development of the orbital elements of satellites, can be described with the resulting quadrupole moment.

Gravitational waves

In the theory of gravitational waves, the quadrupole is of fundamental importance. Since there are no time-varying gravitational dipoles, the lowest order of gravitational waves is quadrupole radiation, which corresponds to the shape of the propagation of electromagnetic quadrupole radiation.

Higher multipoles

Similarly, higher multipoles can be treated, so-called octupoles, for example by alternating point charges on the eight corners of a parallelepiped , e.g. B. a cube with edge length a , with the "octupole limit" (or more generally: a single 2 ^l pole is approximated by superimposing two displaced 2 ⁽^l⁻¹⁾ poles with opposite signs ). ${\ displaystyle \ {\ lim _ {a \ to 0; \, a ^ {3} Q = {\ text {const.}}} \ dots \}}$

Specialist literature

Horst Stöcker: Pocket book of physics. 4th edition, Verlag Harry Deutsch, Frankfurt am Main 2000, ISBN 3-8171-1628-4 .

Web links

Commons : Quadrupoles - collection of images, videos, and audio files

Individual evidence

^ Dieter Meschede: Optics, light and laser . Vieweg + Teubner, Wiesbaden 2008, ISBN 978-3-8351-0143-2 , pp. 568 .
↑ Ulrich E. Schröder: Gravitation: An introduction to the general theory of relativity . Harri Deutsch Verlag, Frankfurt am Main 2007, ISBN 978-3-8171-1798-7 , pp. 133 ( limited preview in Google Book search).

[1] Dieter Meschede: Optics, light and laser . Vieweg + Teubner, Wiesbaden 2008, ISBN 978-3-8351-0143-2 , pp. 568 .

[2] Ulrich E. Schröder: Gravitation: An introduction to the general theory of relativity . Harri Deutsch Verlag, Frankfurt am Main 2007, ISBN 978-3-8171-1798-7 , pp. 133 ( limited preview in Google Book search).