Mercury telluride

from Wikipedia, the free encyclopedia
Crystal structure
Crystal structure of mercury telluride
__ Hg 2+      __ Te 2−
General
Surname Mercury telluride
other names

Mercury (II) telluride

Ratio formula HgTe
Brief description

black crystals

External identifiers / databases
CAS number 12068-90-5
EC number 235-108-9
ECHA InfoCard 100.031.905
PubChem 82914
Wikidata Q412491
properties
Molar mass 329.18 g mol −1
Physical state

firmly

density

8.12 g cm −3 (20 ° C)

Melting point

673 ° C

safety instructions
GHS hazard labeling from  Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary
06 - Toxic or very toxic 08 - Dangerous to health 09 - Dangerous for the environment

danger

H and P phrases H: 300-310-330-373-410
P: 260-301 + 310-320-361-405-501
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Mercury telluride (HgTe) is a crystalline compound from the group of Telluride consisting of mercury and tellurium having a (cubic) sphalerite - crystal structure is formed. The space group is F 4 3 m (No. 216) . In its crystalline form it is a direct semiconductor and one of the II-VI compound semiconductors . Template: room group / 216

Occurrence

In nature, mercury telluride is a rare mineral coloradoite .

properties

The naturally weak p-conductive semiconductor material mercury telluride can be converted into an n-conductive semiconductor by doping it with elements such as bromine , aluminum , gallium or indium ; when doped with zinc or copper , the p-conductivity can be increased.

Mercury telluride can be produced by the metal-organic gas phase epitaxy . Applications are in the field of solid state physics as a topological insulator .

Related links

literature

  • Ed. J. Brice, P. Capper: Properties of mercury cadmium telluride . EMIS datareview, INSPEC, IEE, London 1987.

Individual evidence

  1. a b c d e data sheet mercury telluride at AlfaAesar, accessed on July 11, 2011 ( PDF )(JavaScript required) .
  2. Not explicitly listed in Regulation (EC) No. 1272/2008 (CLP) , but with the specified labeling falls under the group entry inorganic compounds of mercury with the exception of mercuric sulphide and those specified elsewhere in this Annex in the Classification and Labeling Inventory of European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .