Tetrabutylammonium fluoride

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Structural formula
Structural formula of tetrabutylammonium fluorideF-.svg
General
Surname Tetrabutylammonium fluoride
other names
  • Tetra- n -butylammoniumfluorid
  • TBAF
Molecular formula (C 4 H 9 ) 4 NF
Brief description

colorless solid (hydrate)

External identifiers / databases
CAS number
  • 429-41-4
  • 22206-57-1 (hydrate)
  • 87749-50-6 (trihydrate)
PubChem 2724141
Wikidata Q423664
properties
Molar mass 261.46 g mol −1
Physical state

firmly

Melting point

62–63 ° C (hydrate)

safety instructions
GHS labeling of hazardous substances

hydrate

05 - Corrosive

danger

H and P phrases H: 314
P: 280-305 + 351 + 338-310
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Tetrabutylammonium fluoride is a chemical compound from the group of quaternary ammonium compounds and fluorides .

properties

Tetrabutylammonium fluoride is a corrosive solid that is sold as a technical product as a mixture with aluminum oxide or as a solution with tetrahydrofuran .

use

The hydrate is tetrabutylammonium fluoride, for. B. for the production of olefins from primary alkyl iodides, as a catalyst ( phase transfer catalysis ) or for the cleavage of silyl ethers , which often serve as protective groups for alcohols.

Individual evidence

  1. a b c Entry on Tetrabutylammonium Fluoride Hydrate at TCI Europe, accessed on June 27, 2011.
  2. a b c d data sheet Tetrabutylammonium fluoride hydrate from Sigma-Aldrich , accessed on April 24, 2011 ( PDF ).