1,4-diiodobutane

Structural formula
General
Surname	1,4-diiodobutane
other names	Tetramethylene diiodide
Molecular formula	C 4 H 8 I 2
Brief description	light yellow liquid
External identifiers / databases
EC number	211-032-1
ECHA InfoCard	100.010.030
PubChem	12337
ChemSpider	11832
Wikidata	Q60982558
properties
Molar mass	309.92 g mol −1
Physical state	liquid
density	2.350 g cm −3
Melting point	5-7 ° C
boiling point	108-110 ° C (10 mmHg)
solubility	practically insoluble in water
Refractive index	1.6212 (20 ° C)
safety instructions
GHS labeling of hazardous substances Caution
H and P phrases	H: 315-319
	P: 280-264-305 + 351 + 338-321-332 + 313-337 + 313
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

1,4-Diiodobutane is a chemical compound from the group of aliphatic , saturated halogenated hydrocarbons .

Extraction and presentation

1,4-Diiodobutane can be obtained by reacting tetrahydrofuran with iodine and phosphorus . It can also be prepared by reacting trimethyliodosilane with trimethyl- (4-iodobutoxy) silane.

properties

1,4-Diiodobutane is a light yellow liquid that is practically insoluble in water. The connection is stabilized with copper .

use

1,4-Diiodobutane is used as an additive to improve the performance of perovskite solar cells . It is also used as a crosslinking agent for the synthesis of anion exchange membranes from cellulose .

Individual evidence

↑ ^a ^b Data sheet 1,4-Diiodobutane, ≥99%, contains copper as stabilizer from Sigma-Aldrich , accessed on October 31, 2018 ( PDF ).
↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j data sheet 1,4-diiodobutane, 99%, stab. with copper at AlfaAesar, accessed on October 31, 2018 ( PDF )(JavaScript required) .
^ GB Heisig: 1,4-Diiodobutane from Tetrahydrofuran. In: Journal of the American Chemical Society. 61, 1939, p. 525, doi : 10.1021 / ja01871a507 .
↑ MG Voronkov, VE Puzanova u. a .: Cleavage of tetrahydrofuran by trimethyliodosilane. In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24, 1975, p. 377, doi : 10.1007 / BF00925793 .

[Sigma-1] Data sheet 1,4-Diiodobutane, ≥99%, contains copper as stabilizer from Sigma-Aldrich , accessed on October 31, 2018 ( PDF ).

[Alfa-2] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j data sheet 1,4-diiodobutane, 99%, stab. with copper at AlfaAesar, accessed on October 31, 2018 ( PDF )(JavaScript required) .

[DOI10.1021/ja01871a507-3] GB Heisig: 1,4-Diiodobutane from Tetrahydrofuran. In: Journal of the American Chemical Society. 61, 1939, p. 525, doi : 10.1021 / ja01871a507 .

[DOI10.1007/BF00925793-4] MG Voronkov, VE Puzanova u. a .: Cleavage of tetrahydrofuran by trimethyliodosilane. In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24, 1975, p. 377, doi : 10.1007 / BF00925793 .