1,1-diiodoethane

Structural formula
General
Surname	1,1-diiodoethane
other names	1,1-ethylidene diiodide
Molecular formula	C 2 H 4 I 2
External identifiers / databases
EC number	209-821-0
ECHA InfoCard	100.008.930
PubChem	68980
Wikidata	Q161288
properties
Molar mass	281.8 g mol −1
Physical state	liquid
density	2.84 g cm −3
Melting point	−60 ° C
boiling point	177-179 ° C; 61–61 ° C (16 h Pa );
safety instructions
GHS labeling of hazardous substances Caution
H and P phrases	H: 302-315-319-335
	P: 261-305 + 351 + 338
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

1,1-Diiodoethane is a chemical compound that belongs to the halogen alkanes . It is a liquid with a boiling point of 177–179 ° C and a high density of 2.84 g · cm ⁻³ . It is isomeric to 1,2-diiodoethane .

presentation

1,1-Diiodoethane can be made from diazoethane and elemental iodine . The starting material for the production of the diazoethane is ethylamine hydrochloride, which is converted into nitrosoethylurea.

properties

The critical point of 1,1-diiodoethane is at a temperature of 723.89 K, a pressure of 47.83 bar and a volume of 317.5 ml · mol ⁻¹ . The enthalpy of vaporization at the boiling point is 40.882 kJ / mol.

Individual evidence

↑ ^a ^b ^c Dictionary of organic compounds, p. 2495 ( limited preview in Google book search).
^ ^A ^b C. L. Yaws: Thermophysical properties of chemicals and hydrocarbons , 1st edition, p. 6, William Andrew Inc., New York, 2008 . ISBN 0-8155-1596-0 ( limited preview in Google Book Search).
↑ ^a ^b data sheet 1,1-diiodoethane from Sigma-Aldrich , accessed on May 12, 2011 ( PDF ).
↑ RC Neuman Jr., ML Rahm: Synthesis and Nuclear Magnetic Resonance Spectra of Some 1-Halo-1-iodoalkanes , in: J. Org. Chem. , 1966 , 31 , pp. 1857-1859; doi : 10.1021 / jo01344a041 .
↑ F. Arndt: Nitrosomethylurea In: Organic Syntheses . 15, 1935, p. 48, doi : 10.15227 / orgsyn.015.0048 ; Coll. Vol. 2, 1943, p. 461 ( PDF ).
↑ F. Arndt: Diazomethane In: Organic Syntheses . 15, 1935, p. 3, doi : 10.15227 / orgsyn.015.0003 ; Coll. Vol. 2, 1943, p. 156 ( PDF ).
^ CL Yaws: Thermophysical properties of chemicals and hydrocarbons , 1st edition, p. 313, William Andrew Inc., New York, 2008 . ISBN 0-8155-1596-0 ( limited preview in Google Book Search).

[DOC-1] Dictionary of organic compounds, p. 2495 ( limited preview in Google book search).

[Yaws_006-2] A ^b C. L. Yaws: Thermophysical properties of chemicals and hydrocarbons , 1st edition, p. 6, William Andrew Inc., New York, 2008 . ISBN 0-8155-1596-0 ( limited preview in Google Book Search).

[Sigma-3] ta sheet 1,1-diiodoethane from Sigma-Aldrich , accessed on May 12, 2011 ( PDF ).

[4] RC Neuman Jr., ML Rahm: Synthesis and Nuclear Magnetic Resonance Spectra of Some 1-Halo-1-iodoalkanes , in: J. Org. Chem. , 1966 , 31 , pp. 1857-1859; doi : 10.1021 / jo01344a041 .

[5] F. Arndt: Nitrosomethylurea In: Organic Syntheses . 15, 1935, p. 48, doi : 10.15227 / orgsyn.015.0048 ; Coll. Vol. 2, 1943, p. 461 ( PDF ).

[6] F. Arndt: Diazomethane In: Organic Syntheses . 15, 1935, p. 3, doi : 10.15227 / orgsyn.015.0003 ; Coll. Vol. 2, 1943, p. 156 ( PDF ).

[7] CL Yaws: Thermophysical properties of chemicals and hydrocarbons , 1st edition, p. 313, William Andrew Inc., New York, 2008 . ISBN 0-8155-1596-0 ( limited preview in Google Book Search).