1-chloroheptane

Structural formula
General
Surname	1-chloroheptane
other names	n -Chlorheptane; Heptyl chloride;
Molecular formula	C 7 H 15 Cl
Brief description	colorless liquid
External identifiers / databases
EC number	211-070-9
ECHA InfoCard	100.010.065
PubChem	12371
Wikidata	Q15726086
properties
Molar mass	134.65 g mol −1
Physical state	liquid
density	0.88 g cm −3
Melting point	−70 ° C
boiling point	159 ° C
Vapor pressure	9.57 hPa (40 ° C); 16.7 hPa (50 ° C);
solubility	practically insoluble in water (14 mg l −1 at 20 ° C)
Refractive index	1.425 (20 ° C)
safety instructions
GHS labeling of hazardous substances Caution
H and P phrases	H: 226
	P: 210-370 + 378
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

1-Chlorheptane is a chemical compound from the group of saturated organic aliphatic halogenated hydrocarbons .

Extraction and presentation

1-Chlorheptane can be obtained by reacting 1-heptanol with thionyl chloride in pyridine .

{\ displaystyle \ mathrm {C_ {7} H_ {15} OH + SOCl_ {2} \ longrightarrow C_ {7} H_ {15} Cl + SO_ {2} + HCl}}

properties

1-Chlorheptane is a moisture-sensitive, little volatile, colorless liquid that is practically insoluble in water. The compound boils at 159 ° C. under normal pressure. According to Antoine, the vapor pressure function results from log ₁₀ (P) = A− (B / (T + C)) (P in bar, T in K) with A = 3.9631, B = 1410.064 and C = −77.511 in the temperature range from 308 K to 433 K. It forms highly flammable vapor-air mixtures. The compound has a flash point of 41 ° C. The ignition temperature is 220 ° C. The substance therefore falls into temperature class T3.

use

1-chloroheptane is used as a synthetic chemical. It was also used when coupling a GC to the ICP-MHMS-FPC for the determination of halogenated hydrocarbons and organometallic compounds.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k ^l ^m ⁿ Entry on 1-chlorheptane in the GESTIS substance database of the IFA , accessed on January 9, 2019(JavaScript required) .
↑ ^a ^b Data sheet 1-chloroheptane, 99% from Sigma-Aldrich , accessed on July 30, 2014 ( PDF ).
^ William Brown, Christopher Foote, Brent Iverson, Eric Anslyn: Organic Chemistry . Cengage Learning, 2008, p. 386 ( limited preview in Google Book Search).
↑ Kemme, HR; Kreps, SI: Vapor pressure of primary n-alkyl chlorides and alcohols in J. Chem. Eng. Data 14 (1969) 98-102, doi : 10.1021 / je60040a011 .
↑ ^a ^b E. Brandes, W. Möller: Safety-related parameters. Volume 1: Flammable Liquids and Gases. Wirtschaftsverlag NW - Verlag für neue Wissenschaft, Bremerhaven 2003.

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k ^l ^m ⁿ Entry on 1-chlorheptane in the GESTIS substance database of the IFA , accessed on January 9, 2019(JavaScript required) .

[Sigma-2] Data sheet 1-chloroheptane, 99% from Sigma-Aldrich , accessed on July 30, 2014 ( PDF ).

[William_Brown,_Christopher_Foote,_Brent_Iverson,_Eric_Anslyn-3] William Brown, Christopher Foote, Brent Iverson, Eric Anslyn: Organic Chemistry . Cengage Learning, 2008, p. 386 ( limited preview in Google Book Search).

[4] Kemme, HR; Kreps, SI: Vapor pressure of primary n-alkyl chlorides and alcohols in J. Chem. Eng. Data 14 (1969) 98-102, doi : 10.1021 / je60040a011 .

[Brandes-5] E. Brandes, W. Möller: Safety-related parameters. Volume 1: Flammable Liquids and Gases. Wirtschaftsverlag NW - Verlag für neue Wissenschaft, Bremerhaven 2003.