Chlorine (I) nitrate

Structural formula
General
Surname	Chlorine (I) nitrate
other names	Chlorine nitrate
Molecular formula	ClNO 3
Brief description	colorless to pale yellowish liquid
External identifiers / databases
PubChem	114934
ChemSpider	102875
Wikidata	Q2563692
properties
Molar mass	97.46 g mol −1
Physical state	liquid
Melting point	−107 ° C
boiling point	22.3 ° C
solubility	soluble in trichlorofluoromethane and tetrachloromethane
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Chlorine (I) nitrate is an inorganic chemical compound from the group of nitrates and is the mixed anhydride of hypochlorous acid and nitric acid .

Extraction and presentation

Chlorine (I) nitrate can be obtained by reacting dichloroxide with nitrous oxide

{\ displaystyle \ mathrm {Cl_ {2} O + N_ {2} O_ {5} \ longrightarrow 2 \ ClNO_ {3}}}

or chlorofluoride can be obtained with anhydrous nitric acid at about −78 ° C.

{\ displaystyle \ mathrm {ClF + ENT_ {3} \ longrightarrow ClNO_ {3} + HF}}

It is also formed in the stratosphere from chlorine monoxide and nitrogen dioxide .

{\ displaystyle \ mathrm {ClO + NO_ {2} + M \ longrightarrow ClNO_ {3} + M}}

properties

Bond lengths and angles in chlorine (I) nitrate

Chlorine (I) nitrate is a colorless to slightly yellowish, easily mobile liquid. With most organic compounds, such as B. ethers and alcohols it reacts explosively.

use

Chlorine (I) nitrate can be used to produce other halogen nitrates.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 337.
↑ ^a ^b Martin Schmeisser: Chlorine (I) nitrate . In: S. Young Tyree, Jr. (Ed.): Inorganic Syntheses . tape 9 . McGraw-Hill Book Company, Inc., 1967, p. 127-130 (English).
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ James J. Margitan: Chlorine nitrate photochemistry. Photolysis products and kinetics of the reaction atomic chlorine + chlorine nitrate (ClONO2) .fwdarw. molecular chlorine + nitrate. In: The Journal of Physical Chemistry. 87, 1983, pp. 674-679, doi : 10.1021 / j100227a029 .
↑ Ralf Steudel : Chemistry of Non-Metals: From Structure and Bond to Application . Walter de Gruyter, 2008, ISBN 3-11-021128-9 , p. 522 ( limited preview in Google Book search).

[brauer-1] ↑ ^a ^b ^c ^d ^e ^f Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 337.

[IS9-2] Martin Schmeisser: Chlorine (I) nitrate . In: S. Young Tyree, Jr. (Ed.): Inorganic Syntheses . tape 9 . McGraw-Hill Book Company, Inc., 1967, p. 127-130 (English).

[NV-3] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[DOI10.1021/j100227a029-4] James J. Margitan: Chlorine nitrate photochemistry. Photolysis products and kinetics of the reaction atomic chlorine + chlorine nitrate (ClONO2) .fwdarw. molecular chlorine + nitrate. In: The Journal of Physical Chemistry. 87, 1983, pp. 674-679, doi : 10.1021 / j100227a029 .

[Ralf_Steudel-5] Ralf Steudel : Chemistry of Non-Metals: From Structure and Bond to Application . Walter de Gruyter, 2008, ISBN 3-11-021128-9 , p. 522 ( limited preview in Google Book search).