Chloroiodomethane

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Structural formula
Structural formula of chloroiodomethane
General
Surname Chloroiodomethane
other names
  • Chloroiodomethane
  • Iodochloromethane
Molecular formula CH 2 ClI
Brief description

yellow liquid

External identifiers / databases
CAS number 593-71-5
EC number 209-804-8
ECHA InfoCard 100.008.915
PubChem 11644
Wikidata Q421730
properties
Molar mass 176.38 g mol −1
Physical state

liquid

density

2.422 g cm −3

boiling point

108-109 ° C

Refractive index

1.582 (20 ° C)

safety instructions
GHS labeling of hazardous substances
07 - Warning

Caution

H and P phrases H: 315-319-335
P: 261-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Chloriodomethane is a chemical compound from the group of aliphatic and saturated halogenated hydrocarbons or dihalomethanes .

Extraction and presentation

Chloriodomethane can be obtained by reacting dichloromethane with sodium iodide in DMF .

properties

Chloriodomethane is a yellow liquid. It crystallizes in the orthorhombic crystal system with the space group Pnma (space group no. 62) and the lattice constants : a = 638.3, b = 670.6, c = 886.7 pm. Template: room group / 62

use

Chloriodomethane is used as a synthetic chemical.

Web links

Commons : Chloriodomethane  - Collection of pictures, videos and audio files

Individual evidence

  1. a b c d e f g Entry for CAS no. 593-71-5 in the GESTIS substance database of the IFA , accessed on January 28, 2012(JavaScript required) .
  2. Data sheet Chloroiodomethane, purum, ≥ 97.0% (GC) from Sigma-Aldrich , accessed on October 22, 2016 ( PDF ).
  3. Sotaro Miyano, Harukichi Hashimoto: Convenient Synthesis of Chloroiodomethane from Dichloromethane and Sodium Iodide in DMF . In: Bulletin of the Chemical Society of Japan . tape 44 , no. 10 , 1971, p. 2864-2865 , doi : 10.1246 / bcsj.44.2864 .
  4. BH Torrie, OS Binbrek, R. Von Dreele: Crystal structure of chloroiodomethane . In: Molecular Physics . tape 79 , no. 4 , 1993, p. 869-874 , doi : 10.1080 / 00268979300101691 .