Hydrazinium bromide

Structural formula
General
Surname	Hydrazinium bromide
other names	Hydrazine hydrobromide; Hydrazine monohydrobromide;
Molecular formula	N 2 H 5 Br
Brief description	colorless and odorless solid
External identifiers / databases
EC number	237-412-7
ECHA InfoCard	100.033.997
PubChem	159693
Wikidata	Q27882236
properties
Molar mass	112.96 g mol −1
Physical state	firmly
density	2.3 g cm −3
Melting point	85 ° C
boiling point	170 ° C (decomposition)
solubility	very easily soluble in water (3260 g l −1 at 25 ° C)
safety instructions
H and P phrases	H: 301 + 311 + 331-317-350-410
	P: 201-273-280-308 + 313-304 + 340-302 + 352-309 + 310
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Hydrazinium bromide is a chemical compound from the group of hydrazinium salts .

Extraction and presentation

Hydrazinium bromide can be obtained by reacting hydrobromic acid with hydrazine .

properties

Hydrazinium bromide is a flammable, hardly ignitable, crystalline, colorless, odorless solid, which is very easily soluble in water. It decomposes when heated. It has a monoclinic crystal structure with the space group C 2 / c (space group no. 15) . Template: room group / 15

use

Hydrazinium bromide can be used in the synthesis of bromostannates and bromostannites by reaction with tin (IV) bromide and as a component of soldering flux .

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on hydrazinium bromide in the GESTIS substance database of the IFA , accessed on January 10, 2017(JavaScript required) .
↑ springer.com: N2H5Br ([N2H5 Br) Crystal Structure - SpringerMaterials], accessed November 18, 2016
↑ Ralph P. Seward: hydrazinium BROMIDE AS A SOLVENT. In: The Journal of Physical Chemistry. 66, 1962, p. 1125, doi : 10.1021 / j100812a037 .
↑ K. Sakurai, Y. Tomiie: The crystal structure of hydrazinium bromide, N2H5Br. In: Acta Crystallographica. 5, 1952, p. 289, doi : 10.1107 / S0365110X52000812 .
↑ Datasheet Hydrazine monohydrobromide, ≥98% from Sigma-Aldrich , accessed on November 18, 2016 ( PDF ).

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on hydrazinium bromide in the GESTIS substance database of the IFA , accessed on January 10, 2017(JavaScript required) .

[springer.com-2] springer.com: N2H5Br ([N2H5 Br) Crystal Structure - SpringerMaterials], accessed November 18, 2016

[DOI10.1021/j100812a037-3] Ralph P. Seward: hydrazinium BROMIDE AS A SOLVENT. In: The Journal of Physical Chemistry. 66, 1962, p. 1125, doi : 10.1021 / j100812a037 .

[DOI10.1107/S0365110X52000812-4] K. Sakurai, Y. Tomiie: The crystal structure of hydrazinium bromide, N2H5Br. In: Acta Crystallographica. 5, 1952, p. 289, doi : 10.1107 / S0365110X52000812 .

[Sigma-5] Datasheet Hydrazine monohydrobromide, ≥98% from Sigma-Aldrich , accessed on November 18, 2016 ( PDF ).