Sodium perrhenate
Crystal structure | ||||||||||||||||
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__ Na + __ Re 7+ __ O 2− | ||||||||||||||||
General | ||||||||||||||||
Surname | Sodium perrhenate | |||||||||||||||
Ratio formula | NaReO 4 | |||||||||||||||
Brief description |
white solid |
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External identifiers / databases | ||||||||||||||||
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properties | ||||||||||||||||
Molar mass | 273.19 g mol −1 | |||||||||||||||
Physical state |
firmly |
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density |
5.39 g cm −3 (25 ° C) |
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Melting point |
414 ° C |
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solubility |
Easily soluble in water (1453 g kg −1 at 30 ° C) |
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safety instructions | ||||||||||||||||
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As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . |
Sodium perrhenate is a chemical compound from the group of perrhenates .
Extraction and presentation
Sodium perrhenate can be obtained by reacting sodium hydroxide with perrhenic acid .
properties
Sodium perrhenate is a white solid that is easily soluble in water and ethanol . It has a tetragonal crystal structure of the Scheelite type with the space group I 4 1 / a (space group no. 88) and the lattice parameters a = 536.2 pm and c = 1171.8 pm.
Individual evidence
- ↑ a b c d e data sheet Sodium perrhenate, 99.99% trace metals basis from Sigma-Aldrich , accessed on August 5, 2013 ( PDF ).
- ↑ a b c Georg Brauer (Ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1633.
- ↑ William T. Smith Jr., Selma Harmon Long, The Salts of Perrhenic Acid. I. The Alkali Metals and Ammonium, J. Am. Chem. Soc., 1948, 70 (1), 354-356.