Sodium perrhenate

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Crystal structure
Crystal structure of sodium perrhenate
__ Na +      __ Re 7+      __ O 2−
General
Surname Sodium perrhenate
Ratio formula NaReO 4
Brief description

white solid

External identifiers / databases
CAS number 13472-33-8
EC number 236-742-9
ECHA InfoCard 100.033.388
PubChem 5107658
Wikidata Q2592158
properties
Molar mass 273.19 g mol −1
Physical state

firmly

density

5.39 g cm −3 (25 ° C)

Melting point

414 ° C

solubility

Easily soluble in water (1453 g kg −1 at 30 ° C)

safety instructions
GHS labeling of hazardous substances
03 - Oxidising 07 - Warning

danger

H and P phrases H: 272-315-319-335
P: 220-261-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Sodium perrhenate is a chemical compound from the group of perrhenates .

Extraction and presentation

Sodium perrhenate can be obtained by reacting sodium hydroxide with perrhenic acid .

properties

Sodium perrhenate is a white solid that is easily soluble in water and ethanol . It has a tetragonal crystal structure of the Scheelite type with the space group I 4 1 / a (space group no. 88) and the lattice parameters a = 536.2 pm and c = 1171.8 pm. Template: room group / 88

Individual evidence

  1. a b c d e data sheet Sodium perrhenate, 99.99% trace metals basis from Sigma-Aldrich , accessed on August 5, 2013 ( PDF ).
  2. a b c Georg Brauer (Ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1633.
  3. William T. Smith Jr., Selma Harmon Long, The Salts of Perrhenic Acid. I. The Alkali Metals and Ammonium, J. Am. Chem. Soc., 1948, 70 (1), 354-356.