Nickel (II) acetylacetonate

Structural formula
General
Surname	Nickel (II) acetylacetonate
other names	Ni (acac) 2 ; Nickel (II) 2,4-pentanedionate; Bis (acetylacetonato) nickel (II);
Molecular formula	C 10 H 14 NiO 4
Brief description	light green solid
External identifiers / databases
ECHA InfoCard	100,019,887
PubChem	5112550
ChemSpider	8010633
Wikidata	Q7028230
properties
Molar mass	256.91 g mol −1
Physical state	firmly
Melting point	230 ° C (decomposition)
Vapor pressure	2.7 hPa (110 ° C)
solubility	soluble in water (4.8 g l −1 ), ethanol and toluene
safety instructions
H and P phrases	H: 302-317-350
	P: 201-280-301 + 312 + 330-308 + 313
Toxicological data	587 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Nickel (II) acetylacetonate is a chemical compound of nickel from the group of acetylacetonates .

Extraction and presentation

Nickel (II) acetylacetonate dihydrate can be obtained by reacting nickel (II) salts with acetylacetonate in the presence of a weak base such as sodium acetate . The dihydrate can easily be converted to anhydrate in a vacuum at 50 ° C.

properties

Nickel (II) acetylacetonate is a light green solid that is soluble in water, ethanol and toluene. In solution, the compound is present as a trimer.

use

Nickel (II) acetylacetonate is used as a catalyst and UV stabilizer. It is also used as a starting material for the production of nickel bis (cyclooctadiene) catalysts and is also used in the deposition of nickel (II) oxide thin films by sol-gel techniques on conductive glass substrates. It is also used in organic synthesis for the production of organometals.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f data sheet nickel (II) acetylacetonate, 95% from Sigma-Aldrich , accessed on May 10, 2019 ( PDF ).
↑ ^a ^b ^c data sheet nickel (II) acetylacetonate (PDF) from Merck , accessed on May 10, 2019.
↑ ^a ^b ^c data sheet nickel (II) 2,4-pentanedionate, 95% from AlfaAesar, accessed on May 10, 2019 ( PDF )(JavaScript required) .
↑ D. Nicholls: The Chemistry of Iron, Cobalt and Nickel Comprehensive Inorganic Chemistry . Elsevier, 2013, ISBN 978-1-4831-4643-0 , pp. 1149 ( limited preview in Google Book Search).
↑ DP GRADDON, EC WATTON: Trimerization of Nickel- (II) Acetylacetonate in Solution. In: Nature. 190, 1961, p. 906, doi : 10.1038 / 190906a0 .
↑ Uglea: oligomer Technology and Applications . CRC Press, 1998, ISBN 978-0-8247-9978-6 , pp. 87 ( limited preview in Google Book search).
^ Edward W. Abel, FGA Stone: Organometallic Chemistry . Royal Society of Chemistry, 1990, ISBN 978-0-85186-671-0 , pp. 359 ( limited preview in Google Book Search).

[Sigma-1] ↑ ^a ^b ^c ^d ^e ^f data sheet nickel (II) acetylacetonate, 95% from Sigma-Aldrich , accessed on May 10, 2019 ( PDF ).

[Merck-2] ta sheet nickel (II) acetylacetonate (PDF) from Merck , accessed on May 10, 2019.

[Alfa-3] ta sheet nickel (II) 2,4-pentanedionate, 95% from AlfaAesar, accessed on May 10, 2019 ( PDF )(JavaScript required) .

[D._Nicholls-4] D. Nicholls: The Chemistry of Iron, Cobalt and Nickel Comprehensive Inorganic Chemistry . Elsevier, 2013, ISBN 978-1-4831-4643-0 , pp. 1149 ( limited preview in Google Book Search).

[DOI10.1038/190906a0-5] DP GRADDON, EC WATTON: Trimerization of Nickel- (II) Acetylacetonate in Solution. In: Nature. 190, 1961, p. 906, doi : 10.1038 / 190906a0 .

[Uglea-6] Uglea: oligomer Technology and Applications . CRC Press, 1998, ISBN 978-0-8247-9978-6 , pp. 87 ( limited preview in Google Book search).

[Edward_W._Abel,_F._G._A._Stone-7] Edward W. Abel, FGA Stone: Organometallic Chemistry . Royal Society of Chemistry, 1990, ISBN 978-0-85186-671-0 , pp. 359 ( limited preview in Google Book Search).