Palmitic acid ethyl ester

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Structural formula
Structural formula of ethyl palmitate
General
Surname Palmitic acid ethyl ester
other names
  • Ethyl palmitate
  • Ethyl hexadecanoate
  • Ethyl hexadecanoate
Molecular formula C 18 H 36 O 2
Brief description

white odorless mass or liquid

External identifiers / databases
CAS number 628-97-7
EC number 211-064-6
ECHA InfoCard 100.010.059
PubChem 12366
ChemSpider 11860
Wikidata Q18354123
properties
Molar mass 284.48 g mol −1
Physical state

liquid or solid, depending on the room temperature

density

0.86 g cm −3

Melting point

24-26 ° C

boiling point

192–194 ° C (13 hPa)

solubility
  • practically insoluble in water
  • miscible with ethanol, dimethyl sulfoxide, chloroform and ethyl acetate
Refractive index

1.440 (20 ° C)

safety instructions
GHS labeling of hazardous substances
no GHS pictograms
H and P phrases H: no H-phrases
P: no P-phrases
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Palmitic acid ethyl ester is a chemical compound from the group of fatty acid esters .

Occurrence

Ethyl palmitate is one of the major volatile compounds found in cooked rice , wine, and Luzhou raw liquor (and other brandies ). It occurs naturally in licorice root and chamomile .

Extraction and presentation

Palmitic acid ethyl ester can be obtained by passing hydrogen chloride through an alcoholic solution of palmitic acid .

properties

Palmitic acid ethyl ester is a flammable, hardly flammable, deliquescent, white and odorless solid mass, which melts at a slightly elevated temperature and which is practically insoluble in water. The compound decomposes above 300 ° C. It occurs in two forms that have a melting point of 19 ° C and 24 ° C.

use

Palmitic acid ethyl ester is used in the production of pharmaceutical creams, ointments, skin and hair oils. It acts as a lubricant on the surface of the skin to keep it soft and smooth. The detection of ethyl myristate , ethyl palmitate, ethyl oleate and ethyl stearate in human hair is determined in medicine as a marker for excessive alcohol consumption .

Individual evidence

  1. a b c d e f g h i Entry on ethyl palmitate in the GESTIS substance database of the IFA , accessed on December 17, 2018(JavaScript required) .
  2. a b Data sheet Ethyl palmitate, 97% from AlfaAesar, accessed on December 19, 2018 ( PDF )(JavaScript required) .
  3. a b Data sheet Ethyl palmitate, ≥95%, FG from Sigma-Aldrich , accessed on December 17, 2018 ( PDF ).
  4. Hans-Dieter Belitz, Werner Grosch: Textbook of food chemistry . Springer-Verlag, 2013, ISBN 978-3-662-08308-6 , pp. 743 ( limited preview in Google Book search).
  5. H.-D. Belitz, W. Grosch: Textbook of food chemistry . Springer-Verlag, 2013, ISBN 978-3-662-08306-2 , pp. 697 ( limited preview in Google Book search).
  6. George Fownes: A Manual of Elementary Chemistry, Theoretical and Practical From the 10th Revised and Corrected English Ed . HC Lea, 1870, p. 622 ( limited preview in Google Book search).
  7. a b Entry on ethyl palmitate. In: Römpp Online . Georg Thieme Verlag, accessed on December 19, 2018.
  8. Axel M. Gressner, Torsten Arndt: Lexicon of Medical Laboratory Diagnostics . Springer-Verlag, 2013, ISBN 978-3-642-12921-6 , pp. 480 ( limited preview in Google Book Search).