Phosphorus oxide fluoride

Structural formula
General
Surname	Phosphorus oxide fluoride
other names	Phosphoryl fluoride; Phosphoryl trifluoride; Phosphorus oxide trifluoride;
Molecular formula	POF 3
Brief description	colorless, pungent smelling gas
External identifiers / databases
EC number	236-776-4
ECHA InfoCard	100.033.419
PubChem	83516
ChemSpider	75351
Wikidata	Q4351241
properties
Molar mass	103.97 g mol −1
Physical state	gaseous
density	4.562 kg m −3
Melting point	−39.7 ° C
boiling point	−39.1 ° C
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Phosphorus oxide fluoride is an inorganic chemical compound of phosphorus from the group of fluorides .

Extraction and presentation

Phosphorus oxide fluoride can be obtained by reacting phosphorus oxychloride with hydrogen fluoride at 65 ° C and antimony (V) chloride as a catalyst .

{\ displaystyle \ mathrm {POCl_ {3} +3 \ HF \ longrightarrow POF_ {3} +3 \ HCl}}

Zinc (II) fluoride , lead (II) fluoride or silver (I) fluoride can also be used as fluorinating agents .

properties

Phosphorus oxide fluoride is a colorless, pungent smelling gas that smokes only weakly in the air. Its critical temperature is 73.3 ° C and the critical pressure is 43 bar. It attacks glass.

Individual evidence

↑ ^a ^b ^c ^d Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 211.
^ ^A ^b ^c Dale L. Perry: Handbook of Inorganic Compounds, Second Edition . Taylor & Francis US, 2011, ISBN 1-4398-1462-7 , pp. 311 ( limited preview in Google Book search).
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
^ ^A ^b A. F. Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 777.

[brauer-1] Georg Brauer (Ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 211.

[Dale_L._Perry-2] A ^b ^c Dale L. Perry: Handbook of Inorganic Compounds, Second Edition . Taylor & Francis US, 2011, ISBN 1-4398-1462-7 , pp. 311 ( limited preview in Google Book search).

[NV-3] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[HoWi-4] A ^b A. F. Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 777.