Pigment yellow 14

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Structural formula
Structural formula of Pigment Yellow 14
General
Surname Pigment yellow 14
other names
  • 2,2 '- [(3,3'-Dichlorobiphenyl-4,4'-diyl) bis (azo)] bis [N- (2-methylphenyl) -3-oxobutyramide]
  • CI Pigment Yellow 14
  • Pigment yellow 14
  • Pigment yellow 14
  • CI 21095
Molecular formula C 34 H 30 Cl 2 N 6 O 4
Brief description

yellow odorless solid

External identifiers / databases
CAS number 5468-75-7
EC number 226-789-3
ECHA InfoCard 100.024.354
PubChem 93006
Wikidata Q27261565
properties
Molar mass 657.55 g mol −1
Physical state

firmly

density

1.37 g cm −3

solubility

practically insoluble in water

safety instructions
GHS labeling of hazardous substances
no GHS pictograms
H and P phrases H: no H-phrases
P: no P-phrases
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

CI Pigment Yellow 14 is a chemical compound from the group of the disazo and diaryl - pigments .

Extraction and presentation

Pigment Yellow 14 is produced industrially by tetrazotization of 3,3'-dichlorobenzidine , followed by azo coupling to acetoacetylated o -Toluidin recovered.

properties

Pigment Yellow 14 is a flammable, difficult to ignite, yellow, odorless solid that is practically insoluble in water. It decomposes when heated above 308 ° C. It has a crystal structure with space group P 1 (space group no. 1) . Template: room group / 1

use

Pigment Yellow 14 is used as a pigment (for example in packaging and textile printing).

Individual evidence

  1. a b c d e f g Entry on Pigment Yellow 14 in the GESTIS substance database of the IFA , accessed on March 31, 2020(JavaScript required) .
  2. ^ A b Martin U. Schmidt, Robert E. Dinnebier, Holger Kalkhof: Crystal Engineering on Industrial Diaryl Pigments Using Lattice Energy Minimizations and X-ray Powder Diffraction. In: The Journal of Physical Chemistry B. 111, 2007, p. 9722, doi : 10.1021 / jp071731p .
  3. Willy Herbst, Klaus Hunger: Industrial organic pigments production, properties, application . John Wiley & Sons, 2009, ISBN 3-527-62496-1 , pp. 257 ( limited preview in Google Book search).