Primin

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Structural formula
Structural formula of Primin
General
Surname Primin
other names
  • 2-methoxy-6-pentyl-1,4-benzoquinone
  • 2-methoxy-6-pentyl- p -benzoquinone
Molecular formula C 12 H 16 O 3
Brief description

golden yellow crystals

External identifiers / databases
CAS number 15121-94-5
EC number 604-781-4
ECHA InfoCard 100.121.408
PubChem 84800
Wikidata Q20054545
properties
Molar mass 208.25 g mol −1
Physical state

firmly

Melting point
  • 62-63 ° C
  • 67 ° C
solubility

slightly soluble in water

safety instructions
GHS labeling of hazardous substances
07 - Warning 08 - Dangerous to health
H and P phrases H: 302 + 312 + 332-334-317
P: 280-302 + 352-304 + 340-333 + 313-342 + 311
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Primin is a natural product from the group of benzoquinones .

Occurrence

Cup primrose ( Primula obconica )

Primin is found in the glandular hairs of the cup primrose ( Primula obconica ), which is also known trivially as poison primrose and is widely found in the trade as an ornamental plant . The compound was also found in the cowslip ( Primula elatior ) and in the root cortex of Miconia species.

effect

In people with an allergic reaction, Primin causes dermatitis characterized by redness and blistering . The course of this "Primeldermatis", which is often observed in gardeners as an occupational disease, is considered extremely persistent.

Individual evidence

  1. a b c Entry on Primin. In: Römpp Online . Georg Thieme Verlag, accessed on May 16, 2015.
  2. a b c d e data sheet Primin (PDF) from Carl Roth , accessed on May 16, 2015.
  3. Jürgen Falbe, Manfred Regitz: RÖMPP Lexikon Chemie, 10th Edition, 1996-1999 Volume 5: Pl - S . Georg Thieme Verlag, 2014, ISBN 3-13-200041-8 , p. 3551 ( limited preview in Google Book search).
  4. ^ Albert Gossauer: Structure and reactivity of biomolecules , Verlag Helvetica Chimica Acta, Zurich, 2006, ISBN 978-3-906390-29-1 , p. 277.
  5. ^ W. Kreis, I. Barnickel, F. Häfele: Medicinal plants . 2nd Edition. Botanical Garden of the University of Erlangen - Nuremberg, Erlangen 2001, OCLC 601127546 , p. 22 .