Rhodium (III) nitrate

from Wikipedia, the free encyclopedia
Structural formula
No drawing available
General
Surname Rhodium (III) nitrate
other names

Rhodium trinitrate

Molecular formula Rh (NO 3 ) 3
Brief description

olive brown solid (dihydrate)

External identifiers / databases
CAS number
  • 10139-58-9
  • 13465-43-5 (dihydrate)
EC number 233-397-6
ECHA InfoCard 100.030.348
PubChem 150190
ChemSpider 132398
Wikidata Q18213083
properties
Molar mass 288.92 g mol −1
Physical state

firmly

density

2.48 g cm −3

Melting point

600 ° C (decomposition)

solubility
  • practically insoluble in water
  • 1170 g l −1 in water (dihydrate)
safety instructions
GHS labeling of hazardous substances
03 - Oxidising 05 - Corrosive

danger

H and P phrases H: 272-314
P: 220-280-305 + 351 + 338-310
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Rhodium (III) nitrate is an inorganic chemical compound of rhodium from the group of nitrates .

Extraction and presentation

Rhodium (III) nitrate dihydrate can be obtained by reacting rhodium (III) oxide pentahydrate with nitric acid at 70–80 ° C.

properties

Rhodium (III) nitrate dihydrate is an olive-brown solid that is easily soluble in water.

use

Rhodium (III) nitrate is used to produce rhodium and as a catalyst .

Individual evidence

  1. a b c Georg Brauer (Ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1741.
  2. a b c d Data sheet Rhodium (III) nitrate hydrate, ~ 36% rhodium (Rh) basis from Sigma-Aldrich , accessed on June 21, 2018 ( PDF ).
  3. a b Registration dossier on rhodium trinitrate at the European Chemicals Agency (ECHA), accessed on July 30, 2018.
  4. ^ A b William M. Haynes: CRC Handbook of Chemistry and Physics, 97th Edition . CRC Press, 2016, ISBN 978-1-4987-5429-3 , pp. 101 ( limited preview in Google Book search).
  5. Data sheet Rhodium (III) nitrate solution, Rh 10-15% w / w (cont.Rh) from AlfaAesar, accessed on June 21, 2018 ( PDF )(JavaScript required) .