Silver hexafluoroantimonate (V)

Crystal structure
	__ Ag + __ Sb 5+ __ F -
Crystal system	cubic
Space group	Ia 3 (No. 206)
Lattice parameters	a = ?? 979.85 (4) pm, Z = 8
Coordination numbers	[8] Ag, [6] Sb
General
Surname	Silver (I) -hexafluoroantimonate (V)
Ratio formula	Ag [SbF 6 ]
Brief description	beige powder
External identifiers / databases
EC number	247-429-1
ECHA InfoCard	100.043.102
PubChem	16687962
ChemSpider	11451627
Wikidata	Q36426856
properties
Molar mass	343.62 g mol −1
Physical state	firmly
solubility	soluble in water
safety instructions
H and P phrases	H: 302-314-332-411
	P: 273-280-301 + 312-304 + 340
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Silver hexafluoroantimonate , Ag [SbF ₆ ] is a chemical compound between silver and hexafluoroantimonic acid .

properties

Silver hexafluoroantimonate is a beige powder. It is soluble in water. At room temperature the compound crystallizes in the cubic space group Ia 3 (space group no. 206) in a structure similar to the cesium chloride type. The lattice constants are a = ?? 979.85 (4) pm and Z = 8. Template: room group / 206

use

Silver hexafluoroantimonate can be used as a catalyst.

safety instructions

In oral ingestion or inhalation , the compound is toxic. The eyes can become irritated. Symptoms after exposure to silver hexafluoroantimonate are inflammation and edema of the larynx as well as the bronchi and lungs . Nausea and headache are other signs.

Strong oxidizing agents can react violently with the salt. During the decomposition, hydrogen fluoride and antimony oxides can be released.

Individual evidence

↑ ^a ^b Kazuhiko Matsumotoa, Rika Hagiwaraa, Yasuhiko Itoa, Osamu Tamada: Crystal structures of AgAF ₆ (A = P, As, Sb, Nb, Ta) at ambient temperatures . In: Journal of Fluorine Chemistry . tape 110 , no. 2 , August 2001, p. 117-122 , doi : 10.1016 / S0022-1139 (01) 00418-3 .
↑ ^a ^b ^c ^d data sheet Silver hexafluoroantimonate (V) from Sigma-Aldrich , accessed on February 16, 2019 ( PDF ).
↑ ^a ^b ^c ^d ^e data sheet Silver (I) hexafluoroantimonate at AlfaAesar, accessed on February 16, 2019 ( PDF )(JavaScript required) .
^ Mathieu Bui The Thuong, André Mann, Alain Wagner: Mild chemo-selective hydration of terminal alkynes catalysed by AgSbF6. In: Chem. Commun. 48, 2012, p. 434, doi : 10.1039 / C1CC12928G .
↑ Ian Fairlamb, Jason Lynam: Organometallic Chemistry . Royal Society of Chemistry, 2015, ISBN 978-1-84973-984-9 , pp. 62 ( limited preview in Google Book search).

[Kristallstruktur-1] Kazuhiko Matsumotoa, Rika Hagiwaraa, Yasuhiko Itoa, Osamu Tamada: Crystal structures of AgAF ₆ (A = P, As, Sb, Nb, Ta) at ambient temperatures . In: Journal of Fluorine Chemistry . tape 110 , no. 2 , August 2001, p. 117-122 , doi : 10.1016 / S0022-1139 (01) 00418-3 .

[ALDRICH-2] ta sheet Silver hexafluoroantimonate (V) from Sigma-Aldrich , accessed on February 16, 2019 ( PDF ).

[ALFA-3] ↑ ^a ^b ^c ^d ^e data sheet Silver (I) hexafluoroantimonate at AlfaAesar, accessed on February 16, 2019 ( PDF )(JavaScript required) .

[DOI10.1039/C1CC12928G-4] Mathieu Bui The Thuong, André Mann, Alain Wagner: Mild chemo-selective hydration of terminal alkynes catalysed by AgSbF6. In: Chem. Commun. 48, 2012, p. 434, doi : 10.1039 / C1CC12928G .

[Ian_Fairlamb,_Jason_Lynam-5] Ian Fairlamb, Jason Lynam: Organometallic Chemistry . Royal Society of Chemistry, 2015, ISBN 978-1-84973-984-9 , pp. 62 ( limited preview in Google Book search).