Xenon monofluoridofluorosulfonate

Crystal structure
	__ Xe 2+ __ S 6+ __ O 2− __ F -
Crystal system	orthorhombic
Space group	Pbca (No. 61)
Lattice parameters	a = 9.88 ± 0.01 Å ; b = 10 ± 0.01 Å; c = 10.13 ± 0.01 Å;
General
Surname	Xenon monofluoridofluorosulfonate
other names	Xenon monofluoridofluorosulfate
Ratio formula	XeFSO 3 F
Brief description	colorless solid
External identifiers / databases
Wikidata	Q63441404
properties
Molar mass	249.4 g mol −1
Physical state	firmly
Melting point	36.6 ° C
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Xenonmonofluoridofluorosulfonat , XeFSO ₃ F is an inorganic chemical compound of xenon Monofluoride - cation XeF ⁺ and fluorosulfonic .

Extraction and presentation

The reaction of xenon difluoride and fluorosulfonic acid produces the salt. This all happens at -75 ° C.

${\ displaystyle {\ ce {XeF2 + HSO3F -> XeFSO3F + HF}}}$

properties

Physical properties

The crystal structure of the compound is orthorhombic . It has the space group Pbca (space group no. 61) . Xenon monofluoridofluorosulfonate has the lattice parameters a = 9.88 ± 0.01 Å , b = 10 ± 0.01 Å and c = 10.13 ± 0.01 Å. Template: room group / 61

Chemical properties

The salt melts at 36.6 ° C and turns into a yellow-green liquid. XeFSO ₃ F is thermodynamically unstable and decompose at 20 ° C to xenon , xenon difluoride and Peroxydisulfuryldifluorid .

${\ displaystyle {\ ce {2 XeFSO3F -> Xe + XeF2 + S2O6F2}}}$

In the vacuum sublimed Xenonmonofluoridofluorosulfonat already at 20 ° C.

Individual evidence

^ ^A ^b ^c Hans-Georg Horn, Hiltrud Hein, Karl-Christian Buschbeck, Walter Lippert, Adolf Slawisch: Noble gas compounds . Springer-Verlag, 2013, ISBN 3-662-11600-6 , p. 126 .
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
↑ ^a ^b Neil. Bartlett, M. Wechsberg, GR Jones, RD Burbank: Crystal structure of xenon (II) fluoride fluorosulfate, FXeOSO2F . Inorg. Chem., May 1972, pp. 1124-1127 , doi : 10.1021 / ic50111a042 .

[Edelgasverbindungen-1] A ^b ^c Hans-Georg Horn, Hiltrud Hein, Karl-Christian Buschbeck, Walter Lippert, Adolf Slawisch: Noble gas compounds . Springer-Verlag, 2013, ISBN 3-662-11600-6 , p. 126 .

[NV-2] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[FXeOSO2F-3] Neil. Bartlett, M. Wechsberg, GR Jones, RD Burbank: Crystal structure of xenon (II) fluoride fluorosulfate, FXeOSO2F . Inorg. Chem., May 1972, pp. 1124-1127 , doi : 10.1021 / ic50111a042 .