CLT acid

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Structural formula
Structural formula of CLT acid
General
Surname CLT acid
other names
  • 2-Amino-5-chloro-4-methylbenzenesulfonic acid ( IUPAC )
  • 2-amino-5- chloro - p -toluenesulfonic acid
Molecular formula C 7 H 8 ClNO 3 S
Brief description

white to slightly reddish powder

External identifiers / databases
CAS number 88-53-9
EC number 201-839-7
ECHA InfoCard 100.001.672
PubChem 6936
ChemSpider 6670
Wikidata Q17521832
properties
Molar mass 221.664 g mol −1
Physical state

firmly

Melting point

> 400 ° C

safety instructions
GHS labeling of hazardous substances
05 - Corrosive

danger

H and P phrases H: 314
P: 280-305 + 351 + 338-310
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

The CLT acid is a chemical compound from the group of toluenesulfonic acids . It is used as a diazo component in the synthesis of azo dyes .

use

By diazotization of the CLT-acid with sodium nitrite and hydrochloric acid and subsequent coupling with 2-naphthol to obtain the sodium salt of Pigment Red 53 (Lake Red C). By laking with barium salts 1 which is used in large amounts primarily in printing inks: obtained Pigment Red 53rd The strontium and calcium salts (Pigment Red 53: 3 and Pigment Red 53: 2) are also known, but of lesser economic importance.

Individual evidence

  1. Chemicalland21: data sheet CLT-ACID
  2. a b c Data sheet 2-AMINO-5-CHLORO-P-TOLUENESULFONIC ACID, Aldrich at Sigma-Aldrich , accessed on July 4, 2014 ( PDF ).
  3. Willy Herbst, Klaus Hunger: Industrial Organic Pigments . Wiley-VCH, Weinheim 2009, ISBN 978-3-527-62496-6 , pp. 196 f . ( limited preview in Google Book search).
  4. Patent EP0965617 : New crystal modification of the pigment CI Pigment Red 53: 2 (gamma phase). Registered on June 5, 1999 , published on December 22, 1999 , applicant: Clariant GmbH, inventor: Martin U. Schmidt, Hans Joachim Metz.