Quinuclidine
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| General | |||||||||||||||||||
| Surname | Quinuclidine | ||||||||||||||||||
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| Molecular formula | C 7 H 13 N | ||||||||||||||||||
| Brief description |
colorless solid |
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| properties | |||||||||||||||||||
| Molar mass | 111.18 g mol −1 | ||||||||||||||||||
| Physical state |
firmly |
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| density |
1.1334 g cm −3 (48 ° C) |
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| Melting point |
158-160 ° C |
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| Vapor pressure |
1.5 mmHg (20 ° C) |
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| As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . | |||||||||||||||||||
Quinuclidine is a bicyclic, tertiary amine . It is structurally similar to DABCO , which also has a nitrogen atom on the second bridgehead.
Occurrence
Quinuclidine occurs in both quinine and quinidine , as well as in other quinoline alkaloids .
use
Quinuclidine, which is immobilized on an ionic liquid , can be used as a catalyst for a Baylis-Hillman reaction .
Individual evidence
- ↑ a b c Entry on quinuclidine. In: Römpp Online . Georg Thieme Verlag, accessed on February 26, 2020.
- ↑ a b c data sheet Quinuclidine from Sigma-Aldrich , accessed on February 26, 2020 ( PDF ).
- ↑ Xueling Mi, Sanzhong Luo, Jin-Pei Cheng: Ionic Liquid-Immobilized Quinuclidine-Catalyzed Morita - Baylis - Hillman Reactions . In: The Journal of Organic Chemistry . tape 70 , no. 6 , March 2005, p. 2338-2341 , doi : 10.1021 / jo048391d .