Cobalt (III) sulfate

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General
Surname Cobalt (III) sulfate
other names

Dicobalt trisulfate

Molecular formula Co 2 (SO 4 ) 3
Brief description

blue-green solid

External identifiers / databases
CAS number 13478-09-6
EC number 236-772-2
ECHA InfoCard 100.033.415
PubChem 9822593
ChemSpider 7998342
Wikidata Q4445802
properties
Molar mass 730.37 g mol −1
Physical state

firmly

solubility
  • Decomposes in water
  • Soluble in dilute sulfuric acid
safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Cobalt (III) sulfate is an inorganic chemical compound of cobalt from the group of sulfates .

Extraction and presentation

Cobalt (III) sulfate 18 hydrate (Co 2 (SO 4 ) 3 · 18H 2 O) can be obtained by anodic oxidation of a sulfuric acid solution of cobalt (II) sulfate heptahydrate at 0 ° C.

properties

Cobalt (III) sulfate is a solid that is present as blue-green, shiny flakes. It is a powerful oxidizing agent and quickly decomposes in a dry atmosphere when heated to a brown, then reddish powder. Ice-cold water rapidly decomposes with the formation of oxygen and cobalt (II) sulfate. With dilute sulfuric acid , it forms a green solution that is stable for a few days. When mixed with alkali, cobalt oxide hydroxide is deposited . With alkali metal sulfates it forms dark blue cobalt alum , e.g. B. Potassium cobalt sulfate dodecahydrate KCo (SO 4 ) 2 · 12H 2 O.

Individual evidence

  1. a b c d e f Georg Brauer (Ed.) U. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0 , p. 1668.
  2. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  3. ^ AF Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 1556.