Decanenitrile

Structural formula
General
Surname	Decanenitrile
other names	Nonanoyl cyanide; Capric acid nitrile; 1-cyannonane;
Molecular formula	C 10 H 19 N
Brief description	white to yellowish liquid with an ammonia-like odor
External identifiers / databases
EC number	217-830-6
ECHA InfoCard	100.016.210
PubChem	74791
ChemSpider	67360
Wikidata	Q27251754
properties
Molar mass	153.27 g mol −1
Physical state	liquid
density	0.82 g cm −3
Melting point	−15 ° C
boiling point	243 ° C
solubility	practically insoluble in water; very soluble in acetone , diethyl ether , ethanol and chloroform ;
Refractive index	1.4300 (20 ° C)
safety instructions
H and P phrases	H: 315-410
	P: 273-280-302 + 352-332 + 313-362-501
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Decanenitrile is a chemical compound from the group of nitriles .

Extraction and presentation

Decanenitrile can be obtained by reacting 1-bromononane with sodium cyanide in dimethyl sulfoxide (DMSO) as a solvent as part of a nucleophilic substitution .

A second-order nucleophilic substitution takes place and, when polar aprotic solvents (e.g. DMSO) are used, yields of decanenitrile of about 93%.

properties

Decanenitrile is a flammable, hardly inflammable, light-sensitive, white to yellowish liquid with an ammonia- like odor, which is practically insoluble in water.

Web links

Commons : Decannitril - Collection of images, videos and audio files

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ Entry on decanenitrile in the GESTIS substance database of the IFA , accessed on January 2, 2019(JavaScript required) .
^ William M. Haynes: CRC Handbook of Chemistry and Physics . CRC Press, 2016, ISBN 978-1-4987-5429-3 , pp. 12 ( limited preview in Google Book search).
↑ Data sheet Decanonitrile, 98% from AlfaAesar, accessed on January 2, 2019 ( PDF )(JavaScript required) .
↑ ^a ^b K. Peter C. Vollhardt, Neil E. Schore, Katrin-M. Roy: Organic chemistry . Ed .: Holger Butenschön. 5th edition. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 2011, ISBN 978-3-527-32754-6 , p. 1058 ( limited preview in Google Book search).

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ Entry on decanenitrile in the GESTIS substance database of the IFA , accessed on January 2, 2019(JavaScript required) .

[William_M._Haynes-2] William M. Haynes: CRC Handbook of Chemistry and Physics . CRC Press, 2016, ISBN 978-1-4987-5429-3 , pp. 12 ( limited preview in Google Book search).

[Alfa-3] Data sheet Decanonitrile, 98% from AlfaAesar, accessed on January 2, 2019 ( PDF )(JavaScript required) .

[VOLLHARDT-4] K. Peter C. Vollhardt, Neil E. Schore, Katrin-M. Roy: Organic chemistry . Ed .: Holger Butenschön. 5th edition. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 2011, ISBN 978-3-527-32754-6 , p. 1058 ( limited preview in Google Book search).