Dienochlor

Structural formula
General
Surname	Dienochlor
other names	Perchlorbis (cyclopenta-2,4-dien-1-yl)
Molecular formula	C 10 Cl 10
Brief description	yellow solid
External identifiers / databases
EC number	218-763-5
ECHA InfoCard	100.017.058
PubChem	16686
Wikidata	Q3032700
properties
Molar mass	474.64 g mol −1
Physical state	firmly
density	1.923 g cm −3 (25 ° C)
Melting point	122-123 ° C
boiling point	250 ° C (decomposition)
solubility	practically insoluble in water
safety instructions
H and P phrases	H: 302-319-400
	P: 273-305 + 351 + 338
Toxicological data	1200 mg kg −1 ( LD 50 , rat , oral ) ; > 6130 mg kg −1 ( LD 50 , rabbit , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Dienochlor is a chemical compound from the group of cyclic chlorinated hydrocarbons .

Extraction and presentation

Dienochlor can be obtained by catalytic reduction of hexachlorocyclopentadiene (e.g. with copper or hydrogen).

properties

Dienochlor is a flammable yellow solid that is practically insoluble in water. It decomposes when heated above 250 ° C. It decomposes rapidly when exposed to sunlight.

use

Dienochlor is used as an acaricide to control mites ( Tetranychus spp. , Red spider and Polyphagotarsonemus latus ) on roses, chrysanthemums and other ornamental plants.

Admission

Dienochlor was approved in the FRG between 1971 and 1990.

In the European Union, dienochlor was not included in Annex I of Directive 91/414 / EEC with Regulation (EC) No. 2076/2002 of November 20, 2002. For this reason, no plant protection products containing dienochlor may be approved in the member states of the EU.

In Germany, Austria and Switzerland, no pesticides with this active ingredient are permitted.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k Entry for CAS no. 2227-17-0 in the GESTIS substance database of the IFA , accessed on March 24, 2013(JavaScript required) .
↑ Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 808 ( limited preview in Google Book search).
^ Entry on dienochlor in the Hazardous Substances Data Bank , accessed March 24, 2013.
↑ ^a ^b Terence Robert Roberts, David Herd Hutson: Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides . Royal Society of Chemistry, 1999, ISBN 0-85404-499-X , pp. 161 ( limited preview in Google Book search).
↑ BVL: Reports on Plant Protection Products 2009 Active Ingredients in Plant Protection Products Authorization history and regulations of the Plant Protection Application Ordinance
↑ Regulation (EC) No. 2076/2002 (PDF) of the Commission of November 20, 2002
↑ General Directorate Health and Food Safety of the European Commission: Entry on dienochlor in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 24, 2016.

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k Entry for CAS no. 2227-17-0 in the GESTIS substance database of the IFA , accessed on March 24, 2013(JavaScript required) .

[Thomas_A._Unger-2] Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 808 ( limited preview in Google Book search).

[HSDB-3] Entry on dienochlor in the Hazardous Substances Data Bank , accessed March 24, 2013.

[Terence_Robert_Roberts,_David_Herd_Hutson-4] Terence Robert Roberts, David Herd Hutson: Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides . Royal Society of Chemistry, 1999, ISBN 0-85404-499-X , pp. 161 ( limited preview in Google Book search).

[BVL-5] BVL: Reports on Plant Protection Products 2009 Active Ingredients in Plant Protection Products Authorization history and regulations of the Plant Protection Application Ordinance

[6] Regulation (EC) No. 2076/2002 (PDF) of the Commission of November 20, 2002

[PSM-7] General Directorate Health and Food Safety of the European Commission: Entry on dienochlor in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 24, 2016.