Iron silicide

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Crystal structure
No drawing available
General
Surname Iron silicide
other names

Iron silicide

Ratio formula FeSi
Brief description

gray odorless solid

External identifiers / databases
CAS number 12022-95-6
EC number 234-670-2
ECHA InfoCard 100.031.506
PubChem 13956050
ChemSpider 13077547
Wikidata Q15628166
properties
Molar mass 83.93 g mol −1
Physical state

firmly

density

6.1 g cm −3

Melting point

1410 ° C

solubility

practically insoluble in water

safety instructions
GHS labeling of hazardous substances
no GHS pictograms
H and P phrases H: no H-phrases
P: no P-phrases
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Iron silicide is one of several inorganic chemical compounds between iron and silicon .

Extraction and presentation

Iron silicide can be obtained by reacting silicon with iron. Organometallic synthesis methods are also known.

properties

Iron silicide is a gray, odorless solid that is practically insoluble in water. It has a cubic crystal structure with the space group P 2 1 3 (space group no. 198) . Other high pressure variants are also known. Template: room group / 198

use

Iron silicide is used for the deoxidation and alloying of steel melts, alloying of cast iron batches and melts (iron foundries), silicothermal reduction of precious metals ( chromium , molybdenum and vanadium ) and others ( niobium , tungsten ), production of some inoculants and nodulizers by alloying (melting). High-purity iron silicide is used for the production of high-permeability steel for electrical transformers, for the production of FeSiMn, FeSiN and SiMn alloys. It is also used as a metal additive.

Individual evidence

  1. a b c d e f g h i data sheet Iron silicide, 99.9% (metals basis) at AlfaAesar, accessed on April 12, 2019 ( PDF )(JavaScript required) .
  2. Eugen Piwowarsky: High quality cast iron (gray cast iron) its properties and the physical metallurgy of its manufacture . Springer-Verlag, 2013, ISBN 978-3-642-53133-0 , pp. 44 ( limited preview in Google Book search).
  3. Google Patents: US20060002838A1 - Iron silicide powder and method for production thereof - Google Patents , accessed April 12, 2019
  4. Manoj K. Kolel-Veetil, Teddy M. Keller: Organometallic Routes into the Nanorealms of Binary Fe-Si Phases. In: Materials. 3, 2010, p. 1049, doi : 10.3390 / ma3021049 .
  5. R. Wartchow, p Gerighausen, M. Binnewies: Redetermination of the crystal structure of iron silicide FeSi. In: Journal of Crystallography - New Crystal Structures. 212, 1997, doi : 10.1524 / ncrs.1997.212.jg.320 .
  6. ^ P. Dobson, David & Vočadlo, Lidunka & G. Wood, Ian. (2002). A new high-pressure phase of FeSi. American mineralogist. 87. doi : 10.2138 / am-2002-5-623 .