Iron silicide
Crystal structure | |||||||||||||||||||
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General | |||||||||||||||||||
Surname | Iron silicide | ||||||||||||||||||
other names |
Iron silicide |
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Ratio formula | FeSi | ||||||||||||||||||
Brief description |
gray odorless solid |
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properties | |||||||||||||||||||
Molar mass | 83.93 g mol −1 | ||||||||||||||||||
Physical state |
firmly |
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density |
6.1 g cm −3 |
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Melting point |
1410 ° C |
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solubility |
practically insoluble in water |
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safety instructions | |||||||||||||||||||
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As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . |
Iron silicide is one of several inorganic chemical compounds between iron and silicon .
Extraction and presentation
Iron silicide can be obtained by reacting silicon with iron. Organometallic synthesis methods are also known.
properties
Iron silicide is a gray, odorless solid that is practically insoluble in water. It has a cubic crystal structure with the space group P 2 1 3 (space group no. 198) . Other high pressure variants are also known.
use
Iron silicide is used for the deoxidation and alloying of steel melts, alloying of cast iron batches and melts (iron foundries), silicothermal reduction of precious metals ( chromium , molybdenum and vanadium ) and others ( niobium , tungsten ), production of some inoculants and nodulizers by alloying (melting). High-purity iron silicide is used for the production of high-permeability steel for electrical transformers, for the production of FeSiMn, FeSiN and SiMn alloys. It is also used as a metal additive.
Individual evidence
- ↑ a b c d e f g h i data sheet Iron silicide, 99.9% (metals basis) at AlfaAesar, accessed on April 12, 2019 ( PDF )(JavaScript required) .
- ↑ Eugen Piwowarsky: High quality cast iron (gray cast iron) its properties and the physical metallurgy of its manufacture . Springer-Verlag, 2013, ISBN 978-3-642-53133-0 , pp. 44 ( limited preview in Google Book search).
- ↑ Google Patents: US20060002838A1 - Iron silicide powder and method for production thereof - Google Patents , accessed April 12, 2019
- ↑ Manoj K. Kolel-Veetil, Teddy M. Keller: Organometallic Routes into the Nanorealms of Binary Fe-Si Phases. In: Materials. 3, 2010, p. 1049, doi : 10.3390 / ma3021049 .
- ↑ R. Wartchow, p Gerighausen, M. Binnewies: Redetermination of the crystal structure of iron silicide FeSi. In: Journal of Crystallography - New Crystal Structures. 212, 1997, doi : 10.1524 / ncrs.1997.212.jg.320 .
- ^ P. Dobson, David & Vočadlo, Lidunka & G. Wood, Ian. (2002). A new high-pressure phase of FeSi. American mineralogist. 87. doi : 10.2138 / am-2002-5-623 .