Potassium tetrachloroaurate (III)

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Crystal structure
Crystal structure of potassium tetrachloroaurate (III)
__ K +      __ Au 3+      __ Cl -
Crystal system

monoclinic

Space group

Pc (No. 7)Template: room group / 7

Lattice parameters
  • a = 8.671  Å
  • b = 6.386 Å
  • c = 12.243 Å
  • β = 95.37 °
General
Surname Potassium tetrachloroaurate (III)
other names

Gold chloride potassium

Ratio formula K [AuCl 4 ]
Brief description

yellow-orange powder

External identifiers / databases
CAS number 13682-61-6
EC number 237-190-1
ECHA InfoCard 100,033,795
PubChem 11337898
ChemSpider 9512843
Wikidata Q4456675
properties
Molar mass 377.86 g mol −1
Physical state

firmly

Melting point

300 ° C

solubility

soluble in water

safety instructions
GHS labeling of hazardous substances
07 - Warning

Caution

H and P phrases H: 315-319-335
P: 261-280-305 + 351 + 338
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Potassium tetrachloroaurate , K [AuCl 4 ] is an inorganic compound of tetrachloroauric acid with the alkali metal potassium .

properties

Potassium tetrachloroaurate is an odorless, yellow-orange powder. The compound is stable and photosensitive under normal conditions . The melting point is approx. 300 ° C. The potassium salt has a monoclinic crystal system with the space group Pc (space group no. 7) . The lattice parameters are a = 8.671  Å , b = 6.386 Å and c = 12.243 Å. The number of degrees of the β angle is 95.37 °. Template: room group / 7

use

Potassium tetrachloroaurate (III) is contained in clay baths. The solution is used to treat albumin paper .

safety instructions

The salt causes irritation on contact with the skin, eyes or respiratory tract. The chemical should not be swallowed as damage can occur.

Potassium tetrachloroaurate reacts violently with ammonia NH 3 , strong oxidizing agents and powdered metals. Combustion of the substance can produce hydrogen chloride , among other things .

Individual evidence

  1. a b c data sheet Potassium tetrachloroaurate (III) from Acros, accessed on February 2, 2019.
  2. a b c d e f data sheet potassium tetrachloroaurate (III) (PDF) from Carl Roth , accessed on February 2, 2019.
  3. M. Bonamico, G. Dessy: The crystal structure of anhydrous potassium tetrachloroaurate (III) . Acta Cryst., 1973, pp. 1735-1736 , doi : 10.1107 / S0567740873005406 .