Nickel (II) sulfite

Structural formula
General
Surname	Nickel (II) sulfite
other names	Nickel sulfite
Molecular formula	NiSO 3
Brief description	Solid
External identifiers / databases
EC number	231-827-7
ECHA InfoCard	100.028.934
PubChem	14029754
Wikidata	Q18002898
properties
Molar mass	138.74 g mol −1
Physical state	firmly
density	2.04 g cm −3 (hexahydrate)
solubility	practically insoluble in water (hexahydrate)
safety instructions
H and P phrases	H: 350i-372-334-317-410
	P: ?
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Nickel (II) sulfite is an inorganic chemical compound of nickel from the group of sulfites .

Extraction and presentation

Nickel (II) sulfite can be obtained by reacting nickel salt solutions such as nickel (II) bromide with sulfites (e.g. sodium sulfite or ammonium sulfite ).

{\ displaystyle \ mathrm {NiBr_ {2} + (NH_ {4}) _ {2} SO_ {3} \ longrightarrow NiSO_ {3} +2 \ NH_ {4} Br}}

properties

Nickel (II) sulfite is a green solid. The hexahydrate, which is practically insoluble in water, crystallizes out of aqueous solutions. This converts 40, 55 and 85 ° C into the tri-, 2.5 and dihydrate. The hexahydrate has a hexagonal crystal structure with the space group R 3 (space group no. 146) . Some sources indicate that there is also a tetragonal modification of the hexahydrate with the space group P 4 / nbm (space group no. 125) . The 2,5 hydrate has a crystal structure with the space group P 4 ₁ 2 ₁ 2 (space group no. 92) , the dihydrate a crystal structure with the space group P 2 ₁ / n (space group no. 14, position 2) . Template: room group / 146 Template: room group / 125 Template: room group / 92 Template: room group / 14.2

Individual evidence

↑ ^a ^b ^c ^d Entry for CAS no. 7757-95-1 in the GESTIS substance database of the IFA , accessed on July 1, 2016(JavaScript required) .
^ ^A ^b S. Baggio, LN Becka: A reinvestigation of the structure of nickel sulphite hexahydrate, NiSO3.6H2O. In: Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 25, p. 1150, doi : 10.1107 / S0567740869003657 .
↑ ^a ^b ^c M.R. Masson, HD Lutz, B. Engelen: Sulfites, Selenites & Tellurites . Elsevier, 2013, ISBN 978-1-4832-8643-3 , pp. 258 ( limited preview in Google Book search).
↑ Entry on nickel (2+) sulphite in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Mark S. Cracolice, Ed Peters: Introductory Chemistry: An Active Learning Approach . Cengage Learning, 2015, ISBN 978-1-305-54501-4 , pp. 262-IA3 ( limited preview in Google Book search).
^ ^A ^b R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 644 ( limited preview in Google Book search).
↑ D. Nicholls: The Chemistry of Iron, Cobalt and Nickel Comprehensive Inorganic Chemistry . Elsevier, 2013, ISBN 978-1-4831-4643-0 , pp. 1131 ( limited preview in Google Book search).
↑ HD Lutz, W. Eckers, B. Engelen: To the knowledge of the sulfites and sulfite hydrates of iron and nickel X-ray, thermoanalytical, IR and Raman spectroscopic investigations. In: Journal of Inorganic and General Chemistry. 475, 1981, p. 165, doi : 10.1002 / zaac.19814750419 .

[GESTIS-1] Entry for CAS no. 7757-95-1 in the GESTIS substance database of the IFA , accessed on July 1, 2016(JavaScript required) .

[DOI10.1107/S0567740869003657-2] A ^b S. Baggio, LN Becka: A reinvestigation of the structure of nickel sulphite hexahydrate, NiSO3.6H2O. In: Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 25, p. 1150, doi : 10.1107 / S0567740869003657 .

[M.R._Masson,_H.D._Lutz,_B._Engelen-3] M.R. Masson, HD Lutz, B. Engelen: Sulfites, Selenites & Tellurites . Elsevier, 2013, ISBN 978-1-4832-8643-3 , pp. 258 ( limited preview in Google Book search).

[CLP_100.028.934-4] Entry on nickel (2+) sulphite in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[Mark_S._Cracolice,_Ed_Peters-5] Mark S. Cracolice, Ed Peters: Introductory Chemistry: An Active Learning Approach . Cengage Learning, 2015, ISBN 978-1-305-54501-4 , pp. 262-IA3 ( limited preview in Google Book search).

[R._Blachnik-6] A ^b R. Blachnik: Pocket book for chemists and physicists Volume 3: Elements, inorganic compounds and materials, minerals . Springer-Verlag, 2013, ISBN 978-3-642-58842-6 , pp. 644 ( limited preview in Google Book search).

[D._Nicholls-7] D. Nicholls: The Chemistry of Iron, Cobalt and Nickel Comprehensive Inorganic Chemistry . Elsevier, 2013, ISBN 978-1-4831-4643-0 , pp. 1131 ( limited preview in Google Book search).

[DOI10.1002/zaac.19814750419-8] HD Lutz, W. Eckers, B. Engelen: To the knowledge of the sulfites and sulfite hydrates of iron and nickel X-ray, thermoanalytical, IR and Raman spectroscopic investigations. In: Journal of Inorganic and General Chemistry. 475, 1981, p. 165, doi : 10.1002 / zaac.19814750419 .